{"title":"利用 SILAR 法在新型膨胀珍珠棉-丁二烯橡胶复合材料上生长 ZnS 纳米粒子","authors":"Nada Edres, Irada Buniyatzadeh, Solmaz Aliyeva, Goncha Eyvazova, Nurlana Binnetova, Naila Guliyeva, Sevinj Mammadyarova, Rasim Alosmanov","doi":"10.1007/s42464-024-00246-6","DOIUrl":null,"url":null,"abstract":"<div><p>The article focuses on synthesising a new nanocomposite incorporating ZnS filler and investigating its structure, optical properties and specific electrical conductivity. In this study, expanded perlite (EP) and butadiene rubber (BR) underwent simultaneous oxidative chlorophosphorylation and subsequent hydrolysis. ZnS nanoparticles were then grown on the crosslinked/ion-exchange composite (EP-PhBR) using the Successive Ionic Layer Adsorption and Reaction (SILAR) method, resulting in the ZnS/EP-PhBR nanocomposite. The structure of the nanocomposite was characterised through UV-Vis spectroscopy and X-ray diffraction analysis. Embedding ZnS nanoparticles in EP-PhBR caused a reduction in the optical band gap from 3.18 eV to 3.045 eV, signifying increased disorder in ZnS nanoparticles due to alterations in the nanocomposite’s intermolecular structure. XRD studies revealed cubic crystal-structured ZnS nanoparticles with an average size of approximately 3 nm in the ZnS/EP-PhBR nanocomposite. The specific electrical conductivity (σ) at ambient temperature demonstrated the enhanced crystallinity of EP-PhBR, attributed to interfacial interactions with ZnS nanoparticles and the developed nanolayers. The ZnS/EP-PhBR nanocomposite exhibited favourable properties, making it a promising material for photocatalysis and solar cell applications.</p></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"27 3","pages":"299 - 308"},"PeriodicalIF":1.2000,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Growing ZnS nanoparticles on novel expanded perlite-butadiene rubber composite by SILAR method\",\"authors\":\"Nada Edres, Irada Buniyatzadeh, Solmaz Aliyeva, Goncha Eyvazova, Nurlana Binnetova, Naila Guliyeva, Sevinj Mammadyarova, Rasim Alosmanov\",\"doi\":\"10.1007/s42464-024-00246-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The article focuses on synthesising a new nanocomposite incorporating ZnS filler and investigating its structure, optical properties and specific electrical conductivity. In this study, expanded perlite (EP) and butadiene rubber (BR) underwent simultaneous oxidative chlorophosphorylation and subsequent hydrolysis. ZnS nanoparticles were then grown on the crosslinked/ion-exchange composite (EP-PhBR) using the Successive Ionic Layer Adsorption and Reaction (SILAR) method, resulting in the ZnS/EP-PhBR nanocomposite. The structure of the nanocomposite was characterised through UV-Vis spectroscopy and X-ray diffraction analysis. Embedding ZnS nanoparticles in EP-PhBR caused a reduction in the optical band gap from 3.18 eV to 3.045 eV, signifying increased disorder in ZnS nanoparticles due to alterations in the nanocomposite’s intermolecular structure. XRD studies revealed cubic crystal-structured ZnS nanoparticles with an average size of approximately 3 nm in the ZnS/EP-PhBR nanocomposite. The specific electrical conductivity (σ) at ambient temperature demonstrated the enhanced crystallinity of EP-PhBR, attributed to interfacial interactions with ZnS nanoparticles and the developed nanolayers. The ZnS/EP-PhBR nanocomposite exhibited favourable properties, making it a promising material for photocatalysis and solar cell applications.</p></div>\",\"PeriodicalId\":662,\"journal\":{\"name\":\"Journal of Rubber Research\",\"volume\":\"27 3\",\"pages\":\"299 - 308\"},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2024-03-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Rubber Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s42464-024-00246-6\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Rubber Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s42464-024-00246-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Growing ZnS nanoparticles on novel expanded perlite-butadiene rubber composite by SILAR method
The article focuses on synthesising a new nanocomposite incorporating ZnS filler and investigating its structure, optical properties and specific electrical conductivity. In this study, expanded perlite (EP) and butadiene rubber (BR) underwent simultaneous oxidative chlorophosphorylation and subsequent hydrolysis. ZnS nanoparticles were then grown on the crosslinked/ion-exchange composite (EP-PhBR) using the Successive Ionic Layer Adsorption and Reaction (SILAR) method, resulting in the ZnS/EP-PhBR nanocomposite. The structure of the nanocomposite was characterised through UV-Vis spectroscopy and X-ray diffraction analysis. Embedding ZnS nanoparticles in EP-PhBR caused a reduction in the optical band gap from 3.18 eV to 3.045 eV, signifying increased disorder in ZnS nanoparticles due to alterations in the nanocomposite’s intermolecular structure. XRD studies revealed cubic crystal-structured ZnS nanoparticles with an average size of approximately 3 nm in the ZnS/EP-PhBR nanocomposite. The specific electrical conductivity (σ) at ambient temperature demonstrated the enhanced crystallinity of EP-PhBR, attributed to interfacial interactions with ZnS nanoparticles and the developed nanolayers. The ZnS/EP-PhBR nanocomposite exhibited favourable properties, making it a promising material for photocatalysis and solar cell applications.
期刊介绍：
The Journal of Rubber Research is devoted to both natural and synthetic rubbers, as well as to related disciplines. The scope of the journal encompasses all aspects of rubber from the core disciplines of biology, physics and chemistry, as well as economics. As a specialised field, rubber science includes within its niche a vast potential of innovative and value-added research areas yet to be explored. This peer reviewed publication focuses on the results of active experimental research and authoritative reviews on all aspects of rubber science.
The Journal of Rubber Research welcomes research on:
the upstream, including crop management, crop improvement and protection, and biotechnology;
the midstream, including processing and effluent management;
the downstream, including rubber engineering and product design, advanced rubber technology, latex science and technology, and chemistry and materials exploratory;
economics, including the economics of rubber production, consumption, and market analysis.
The Journal of Rubber Research serves to build a collective knowledge base while communicating information and validating the quality of research within the discipline, and bringing together work from experts in rubber science and related disciplines.
Scientists in both academia and industry involved in researching and working with all aspects of rubber will find this journal to be both source of information and a gateway for their own publications.
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