对氨基苯环丙基甲基甲基丙烯酸酯与甲基丙烯酸甲酯的 Radical 共聚作用

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED
K. G. Guliyev, V. E. Vahabova
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引用次数: 0

摘要

摘要p-氨基苯基环丙基甲基甲基丙烯酸酯单体的制备及其与甲基丙烯酸甲酯的自由基共聚。通过红外光谱和核磁共振光谱对单体和共聚物进行了表征。测定了单体的相对活性常数,并用 Alfrey-Price 法计算了单体活性和极性。对氨基苯基环丙基甲基甲基丙烯酸酯的共聚常数超过了甲基丙烯酸甲酯的共聚常数,因此共聚物中富含这种单体的单元。基于对氨苯基环丙基甲基甲基丙烯酸酯的共聚物对革兰氏阳性(金黄色葡萄球菌)和革兰氏阴性(大肠杆菌)细菌以及白色念珠菌真菌具有很高的生物活性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Radical Copolymerization of p-Aminophenylcyclopropylmethyl Methacrylate with Methyl Methacrylate

p-Aminophenylcyclopropylmethyl methacrylate monomer was prepared, and its free-radical copolymerization with methyl methacrylate was performed. The monomer and copolymer were characterized by IR and NMR spectroscopy. The relative activity constants of the monomer were determined, and the monomer activity and polarity were calculated by the Alfrey–Price method. The copolymerization constant of p-aminophenylcyclopropylmethyl methacrylate exceeds that of methyl methacrylate; therefore, the copolymer is enriched in units of specifically this comonomer. The copolymers based on p-aminophenylcyclopropylmethyl methacrylate exhibit high biological activity toward Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacteria and toward Candida albicans fungi.

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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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