Thomas E. Shaw, Justin Arami, Jean-François Ayme, Jean-Marie Lehn and Titel Jurca
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Dynamic mechanochemistry: accelerated self-sorting of two imine-based metal complexes under solvent-free mechanochemical conditions†
Self-sorting of two imine-based Cu(I) and Fe(II) coordination complexes from a six-component reagent library has been achieved through solvent-free mechanochemistry. The reaction proceeds rapidly, yielding the thermodynamically favored products in less than 24 hours. The results point to the potential of mechanochemistry to achieve increasingly complex multi-metallic systems through one-pot protocols.
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