{"title":"数字图像比色法测定河流沉积物中铁含量的可行性","authors":"","doi":"10.1016/j.ijsrc.2024.02.005","DOIUrl":null,"url":null,"abstract":"<div><p>The current study describes the development of simple, low-cost, and high-throughput digital image colorimetric methods to determine the total iron concentration in river sediment using the spot-test reactions of iron with 1,10-phenanthroline and thiocyanate. The colorimetric assay was done on 96-microzone plates, and a flatbed scanner was applied to acquire the images. The proposed methods offered a linear range from 0.2 to 14.0 mg/L, with a detection limit of 0.11 mg/kg for the 1,10-phenanthroline method, and, for the thiocyanate method, the linear range comprises 2.0–10.0 mg/L, with a detection limit of 0.28 mg/kg. It was observed that both proposed digital image colorimetric methods (1,10-phenanthroline and thiocyanate) yielded statistically similar results to the reference procedures at a 95% confidence level. A standard reference material (NIST 8704) also was utilized for accuracy assessment and the results were statistically equivalent to the certified values within the 95% confidence level. The digital image colorimetric methods can be an alternative method for iron determination in sediment samples, allowing fast sample screening at a low cost.</p></div>","PeriodicalId":50290,"journal":{"name":"International Journal of Sediment Research","volume":"39 5","pages":"Pages 714-719"},"PeriodicalIF":3.5000,"publicationDate":"2024-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1001627924000180/pdfft?md5=992fdc80aba029805a484f8197083a45&pid=1-s2.0-S1001627924000180-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Feasibility of digital image colorimetric methods for iron determination in river sediment\",\"authors\":\"\",\"doi\":\"10.1016/j.ijsrc.2024.02.005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The current study describes the development of simple, low-cost, and high-throughput digital image colorimetric methods to determine the total iron concentration in river sediment using the spot-test reactions of iron with 1,10-phenanthroline and thiocyanate. The colorimetric assay was done on 96-microzone plates, and a flatbed scanner was applied to acquire the images. The proposed methods offered a linear range from 0.2 to 14.0 mg/L, with a detection limit of 0.11 mg/kg for the 1,10-phenanthroline method, and, for the thiocyanate method, the linear range comprises 2.0–10.0 mg/L, with a detection limit of 0.28 mg/kg. It was observed that both proposed digital image colorimetric methods (1,10-phenanthroline and thiocyanate) yielded statistically similar results to the reference procedures at a 95% confidence level. A standard reference material (NIST 8704) also was utilized for accuracy assessment and the results were statistically equivalent to the certified values within the 95% confidence level. The digital image colorimetric methods can be an alternative method for iron determination in sediment samples, allowing fast sample screening at a low cost.</p></div>\",\"PeriodicalId\":50290,\"journal\":{\"name\":\"International Journal of Sediment Research\",\"volume\":\"39 5\",\"pages\":\"Pages 714-719\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2024-03-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1001627924000180/pdfft?md5=992fdc80aba029805a484f8197083a45&pid=1-s2.0-S1001627924000180-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Sediment Research\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1001627924000180\",\"RegionNum\":2,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Sediment Research","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1001627924000180","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Feasibility of digital image colorimetric methods for iron determination in river sediment
The current study describes the development of simple, low-cost, and high-throughput digital image colorimetric methods to determine the total iron concentration in river sediment using the spot-test reactions of iron with 1,10-phenanthroline and thiocyanate. The colorimetric assay was done on 96-microzone plates, and a flatbed scanner was applied to acquire the images. The proposed methods offered a linear range from 0.2 to 14.0 mg/L, with a detection limit of 0.11 mg/kg for the 1,10-phenanthroline method, and, for the thiocyanate method, the linear range comprises 2.0–10.0 mg/L, with a detection limit of 0.28 mg/kg. It was observed that both proposed digital image colorimetric methods (1,10-phenanthroline and thiocyanate) yielded statistically similar results to the reference procedures at a 95% confidence level. A standard reference material (NIST 8704) also was utilized for accuracy assessment and the results were statistically equivalent to the certified values within the 95% confidence level. The digital image colorimetric methods can be an alternative method for iron determination in sediment samples, allowing fast sample screening at a low cost.
期刊介绍:
International Journal of Sediment Research, the Official Journal of The International Research and Training Center on Erosion and Sedimentation and The World Association for Sedimentation and Erosion Research, publishes scientific and technical papers on all aspects of erosion and sedimentation interpreted in its widest sense.
The subject matter is to include not only the mechanics of sediment transport and fluvial processes, but also what is related to geography, geomorphology, soil erosion, watershed management, sedimentology, environmental and ecological impacts of sedimentation, social and economical effects of sedimentation and its assessment, etc. Special attention is paid to engineering problems related to sedimentation and erosion.