Maricá (Brazil), the new natural hydrogen play which changes the paradigm of hydrogen exploration

Hydrogen exploration in the municipality of Maricá (Rio de Janeiro State, Brazil) indicates that important hydrogen and helium gas fluxes are emitted through reactivated faults. The gas concentrations in the soils, and the modelled gas fluxes, are among the most intense measured so far in the world. This exploration has shown new surface expression of hydrogen micro-seeps, observed along reactivated large tectonic accidents instead of “fairy circles”, most common proxy for hydrogen systems in cratonic formation. The geology of Maricá, consisting in Neoproterozoic metamorphic rocks without any already documented evidence of hydrogen-prone formations, appears as a very new field of investigation for natural hydrogen. Results indicate the presence of systematic hydrogen saturation of the usual detectors plugged at 80 cm depth, as well as a permanent recharge of hydrogen through time, without relaxation time. Moreover, positive helium anomalies are associated with this hydrogen soil gas, proving the existence of a gas flux coming from deep horizons of the subsurface. This reduces the risk of misinterpretation of surface hydrogen measurement, since the fear of drill bit metamorphism or superficial biological activity inducing hydrogen artefacts is always a possibility. These hydrogen and helium micro-seeps are associated with positive thorium concentration superficial anomalies, as it was already observed in other places associated with hydrogen exudations. We present a model of soil gas behavior, with a differential process of adsorption/desorption of each gas compound (N₂, O₂, Ne, H₂ and He), associated with a deep flux of hydrogen and helium. It is possible to assess a quantification of hydrogen flux of 0.32 m³ m⁻².day⁻¹. The surface flux ratio He/H₂ is much higher than any published value of generative flux. This may be explained by a subsurface accumulation, where hydrogen is severely altered whereas helium is preserved, increasing the relative proportion of helium versus hydrogen.