{"title":"利用铽复合物制作用于海水样本中酚筛选的发光微孔板","authors":"Rasha M Kamel","doi":"10.1007/s10895-024-03639-3","DOIUrl":null,"url":null,"abstract":"<p><p>Tb(III)-2-aminoterphthalate complex Tb<sub>2</sub>-(ATPh)<sub>3</sub> was synthesized and characterized using FT-IR, thermal analysis and elemental analysis. Tb<sub>2</sub>(ATPh)<sub>3</sub> microtiter plate was fabricated through embedding Tb(III) complex in polyvinyl chloride membrane and used for environmental determination of phenol in sea water samples. The calculated detection (D<sub>L</sub>), quantification (Q<sub>L</sub>) limits, and binding constant (K<sub>D</sub>) were 00.63 µmol L<sup>- 1</sup>, 2.10 µmol L<sup>- 1</sup> and 1.32 × 10<sup>4</sup> mol<sup>- 1</sup> L, respectively. The fabricated microtiter plates exhibited high selectivity towards phenol over other hydrocarbon compounds. Furthermore, AGREE metric tool was used to assess the method's green nature as well as its practicability and applicability. These merit outcomes provide that the new method for phenol detection was environmentally benign and safe to humans. The prepared Tb<sub>2</sub>(ATPh)<sub>3</sub> MTP was validated through using gas chromatography for monitoring phenol in Suez Bay water accurately with high precision. The obtained results encouraged using Tb<sub>2</sub>(ATPh)<sub>3</sub> MTP for efficient, fast, selective, and direct screening of phenol in real samples.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":"1833-1839"},"PeriodicalIF":2.6000,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11968531/pdf/","citationCount":"0","resultStr":"{\"title\":\"Fabrication of Luminescent Microtiterplate Using Terbium Complex for Phenol Screening in Seawater Samples.\",\"authors\":\"Rasha M Kamel\",\"doi\":\"10.1007/s10895-024-03639-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Tb(III)-2-aminoterphthalate complex Tb<sub>2</sub>-(ATPh)<sub>3</sub> was synthesized and characterized using FT-IR, thermal analysis and elemental analysis. Tb<sub>2</sub>(ATPh)<sub>3</sub> microtiter plate was fabricated through embedding Tb(III) complex in polyvinyl chloride membrane and used for environmental determination of phenol in sea water samples. The calculated detection (D<sub>L</sub>), quantification (Q<sub>L</sub>) limits, and binding constant (K<sub>D</sub>) were 00.63 µmol L<sup>- 1</sup>, 2.10 µmol L<sup>- 1</sup> and 1.32 × 10<sup>4</sup> mol<sup>- 1</sup> L, respectively. The fabricated microtiter plates exhibited high selectivity towards phenol over other hydrocarbon compounds. Furthermore, AGREE metric tool was used to assess the method's green nature as well as its practicability and applicability. These merit outcomes provide that the new method for phenol detection was environmentally benign and safe to humans. The prepared Tb<sub>2</sub>(ATPh)<sub>3</sub> MTP was validated through using gas chromatography for monitoring phenol in Suez Bay water accurately with high precision. The obtained results encouraged using Tb<sub>2</sub>(ATPh)<sub>3</sub> MTP for efficient, fast, selective, and direct screening of phenol in real samples.</p>\",\"PeriodicalId\":15800,\"journal\":{\"name\":\"Journal of Fluorescence\",\"volume\":\" \",\"pages\":\"1833-1839\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2025-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11968531/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Fluorescence\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s10895-024-03639-3\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/3/8 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q2\",\"JCRName\":\"BIOCHEMICAL RESEARCH METHODS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Fluorescence","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10895-024-03639-3","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/3/8 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"BIOCHEMICAL RESEARCH METHODS","Score":null,"Total":0}
Fabrication of Luminescent Microtiterplate Using Terbium Complex for Phenol Screening in Seawater Samples.
Tb(III)-2-aminoterphthalate complex Tb2-(ATPh)3 was synthesized and characterized using FT-IR, thermal analysis and elemental analysis. Tb2(ATPh)3 microtiter plate was fabricated through embedding Tb(III) complex in polyvinyl chloride membrane and used for environmental determination of phenol in sea water samples. The calculated detection (DL), quantification (QL) limits, and binding constant (KD) were 00.63 µmol L- 1, 2.10 µmol L- 1 and 1.32 × 104 mol- 1 L, respectively. The fabricated microtiter plates exhibited high selectivity towards phenol over other hydrocarbon compounds. Furthermore, AGREE metric tool was used to assess the method's green nature as well as its practicability and applicability. These merit outcomes provide that the new method for phenol detection was environmentally benign and safe to humans. The prepared Tb2(ATPh)3 MTP was validated through using gas chromatography for monitoring phenol in Suez Bay water accurately with high precision. The obtained results encouraged using Tb2(ATPh)3 MTP for efficient, fast, selective, and direct screening of phenol in real samples.
期刊介绍：
Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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