通过碘催化分子内环化从相同底物同时合成苯并噻唑及相关多样性类似物

IF 1 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Australian Journal of Chemistry Pub Date : 2024-03-04 DOI:10.1071/ch23144

Meng Cui, Xue-Lin Wang, Mengzhou Wang, Jian-Wu Xie

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引用次数: 0

摘要

为了同时形成一个类似于天然产物苯并噻唑衍生物的化合物库，我们开发了一种简便的β-硫代酮酰胺氧化环化方法。通过对 β-硫代酮酰胺进行氧化环化，可同时生成四类以前未知的苯并噻唑衍生物。这种化学方法的多功能性为获得苯并噻唑衍生物的方法增加了一个有价值的组成部分。

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Simultaneous diversity-oriented synthesis of benzothiazoles and related diverse analogues by iodine-catalyzed intramolecular cyclization from identical substrates

A facile oxidative cyclization of β-ketothioamides for the simultaneous formation of a compound library similar to natural product benzothiazole derivatives has been developed. The oxidative cyclization of β-ketothioamides resulted in the simultaneous formation of four classes of previously unknown benzothiazole derivatives. This chemistry’s versatility adds a valuable component to the methodology for obtaining benzothiazole derivatives.

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来源期刊

Australian Journal of Chemistry 化学-化学综合

CiteScore

2.50

自引率

0.00%

发文量

审稿时长

1.3 months

期刊介绍： Australian Journal of Chemistry - an International Journal for Chemical Science publishes research papers from all fields of chemical science. Papers that are multidisciplinary or address new or emerging areas of chemistry are particularly encouraged. Thus, the scope is dynamic. It includes (but is not limited to) synthesis, structure, new materials, macromolecules and polymers, supramolecular chemistry, analytical and environmental chemistry, natural products, biological and medicinal chemistry, nanotechnology, and surface chemistry. Australian Journal of Chemistry is published with the endorsement of the Commonwealth Scientific and Industrial Research Organisation (CSIRO) and the Australian Academy of Science.