Vjacheslav P Grivin, Svetlana G Matveeva, Roman G Fedunov, Vadim V Yanshole, Danila B Vasilchenko, Evgeni M Glebov
{"title":"(n-Bu4N)2[Pt(NO3)6] 在乙腈中的光化学作用。","authors":"Vjacheslav P Grivin, Svetlana G Matveeva, Roman G Fedunov, Vadim V Yanshole, Danila B Vasilchenko, Evgeni M Glebov","doi":"10.1007/s43630-024-00550-5","DOIUrl":null,"url":null,"abstract":"<p><p>Photochemistry of the (n-Bu<sub>4</sub>N)<sub>2</sub>[Pt(NO<sub>3</sub>)<sub>6</sub>] complex in acetonitrile was studied by means of stationary photolysis and nanosecond laser flash photolysis. The primary photochemical process was found to be an intramolecular electron transfer followed by an escape of an <sup>•</sup>NO<sub>3</sub> radical to the solution bulk. The spectra of two successive Pt(III) intermediates were detected in the microsecond time domain, and their spectral and kinetic characteristics were determined. These intermediates were identified as Pt<sup>III</sup>(NO<sub>3</sub>)<sub>5</sub><sup>2-</sup> and Pt<sup>III</sup>(NO<sub>3</sub>)<sub>4</sub><sup>-</sup> complexes. Disproportionation of Pt(III) species resulted in formation of final Pt(II) products.</p>","PeriodicalId":98,"journal":{"name":"Photochemical & Photobiological Sciences","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photochemistry of (n-Bu<sub>4</sub>N)<sub>2</sub>[Pt(NO<sub>3</sub>)<sub>6</sub>] in acetonitrile.\",\"authors\":\"Vjacheslav P Grivin, Svetlana G Matveeva, Roman G Fedunov, Vadim V Yanshole, Danila B Vasilchenko, Evgeni M Glebov\",\"doi\":\"10.1007/s43630-024-00550-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Photochemistry of the (n-Bu<sub>4</sub>N)<sub>2</sub>[Pt(NO<sub>3</sub>)<sub>6</sub>] complex in acetonitrile was studied by means of stationary photolysis and nanosecond laser flash photolysis. The primary photochemical process was found to be an intramolecular electron transfer followed by an escape of an <sup>•</sup>NO<sub>3</sub> radical to the solution bulk. The spectra of two successive Pt(III) intermediates were detected in the microsecond time domain, and their spectral and kinetic characteristics were determined. These intermediates were identified as Pt<sup>III</sup>(NO<sub>3</sub>)<sub>5</sub><sup>2-</sup> and Pt<sup>III</sup>(NO<sub>3</sub>)<sub>4</sub><sup>-</sup> complexes. Disproportionation of Pt(III) species resulted in formation of final Pt(II) products.</p>\",\"PeriodicalId\":98,\"journal\":{\"name\":\"Photochemical & Photobiological Sciences\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Photochemical & Photobiological Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s43630-024-00550-5\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/3/2 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q3\",\"JCRName\":\"BIOCHEMISTRY & MOLECULAR BIOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Photochemical & Photobiological Sciences","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s43630-024-00550-5","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/3/2 0:00:00","PubModel":"Epub","JCR":"Q3","JCRName":"BIOCHEMISTRY & MOLECULAR BIOLOGY","Score":null,"Total":0}
Photochemistry of (n-Bu4N)2[Pt(NO3)6] in acetonitrile.
Photochemistry of the (n-Bu4N)2[Pt(NO3)6] complex in acetonitrile was studied by means of stationary photolysis and nanosecond laser flash photolysis. The primary photochemical process was found to be an intramolecular electron transfer followed by an escape of an •NO3 radical to the solution bulk. The spectra of two successive Pt(III) intermediates were detected in the microsecond time domain, and their spectral and kinetic characteristics were determined. These intermediates were identified as PtIII(NO3)52- and PtIII(NO3)4- complexes. Disproportionation of Pt(III) species resulted in formation of final Pt(II) products.