Thermally activated structural phase transitions and processes in metal–organic frameworks

The structural knowledge of metal–organic frameworks is crucial to the understanding and development of new efficient materials for industrial implementation. This review classifies and discusses recent advanced literature reports on phase transitions that occur during thermal treatments on metal–organic frameworks and their characterisation. Thermally activated phase transitions and procceses are classified according to the temperaturatures at which they occur: high temperature (reversible and non-reversible) and low temperature. In addition, theoretical calculations and modelling approaches employed to better understand these structural phase transitions are also reviewed.