Jun Chen, Rong Zhang, Caiyan Ma, Peng Zhang, Yonghong Zhang, Bin Wang, Fei Xue, Weiwei Jin, Yu Xia, Chenjiang Liu
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Sustainable electrochemical dearomatization for the synthesis of diverse 2, 3-functionalized indolines
Herein, we achieved a green and efficient dearomatization for the synthesis of 2,3-functionalized polycyclic indolines in an electrochemical way. This avoiding of external oxidants and metals approach allowed various nucleophilic sources (Nu = anilines, TMSN3 and ROH) to perform the products, representing an environmentally benign means. Additionally, the continuous flow electrosynthesis and synthetic transformations also reveal the strong practicality of electrochemistry in organic synthesis.
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