N. V. Zakharova, E. N. Danilovtseva, S. N. Zelinskii, V. V. Annenkov
{"title":"对热和 pH 值敏感的 N-(3-(二乙基氨基)丙基)-N-甲基丙烯酰胺和 N,N-二丙基丙烯酰胺共聚物","authors":"N. V. Zakharova, E. N. Danilovtseva, S. N. Zelinskii, V. V. Annenkov","doi":"10.1134/S0965545X24600042","DOIUrl":null,"url":null,"abstract":"<p>Buffer solutions of random (co)polymers of <i>N</i>-(3-(diethylamino)propyl)-<i>N</i>-methylacrylamide and <i>N</i>,<i>N</i>-dipropylacrylamide, which contain from 0 to 95 mol % of <i>N</i>-(3-(diethylamino)propyl)-<i>N</i>-methyl-acrylamide units and have close molecular weights and the same degrees of polymerization (170 ± 10) are studied by the methods of potentiometric titration, light scattering, turbidimetry, refractometry, and viscometry. The samples are synthesized by the interaction of poly(acryloyl chloride) with <i>N</i>,<i>N</i>-diethyl-<i>N</i> ′-methyl-1,3-propanediamine and dipropylamine. The aqueous solutions are investigated in the concentration range from 0.0001 to 0.0350 g/cm<sup>3</sup> and in pH range from 7.0 to 13.0. Temperature dependences of optical transmission <i>I</i>*, scattered light intensity <i>I</i>, and hydrodynamic sizes of scattering objects are obtained. Phase separation temperatures are determined. The results obtained are comparable with the data available for the previously studied copolymers but containing <i>N</i>-(3-(diethylamino)propyl)-<i>N</i>-methylacrylamide and <i>N</i>,<i>N</i>–diethyl-acrylamide units. It is shown that the structural phase transition and the characteristics of aqueous solutions for the compared copolymers depend on the structure of the (co)polymers and their composition.</p>","PeriodicalId":738,"journal":{"name":"Polymer Science, Series A","volume":"65 6","pages":"637 - 644"},"PeriodicalIF":1.0000,"publicationDate":"2024-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermo- and pH-Sensitive Copolymers of N-(3-(Diethylamino)Propyl)-N-methylacrylamide and N,N-Dipropylacrylamide\",\"authors\":\"N. V. Zakharova, E. N. Danilovtseva, S. N. Zelinskii, V. V. Annenkov\",\"doi\":\"10.1134/S0965545X24600042\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Buffer solutions of random (co)polymers of <i>N</i>-(3-(diethylamino)propyl)-<i>N</i>-methylacrylamide and <i>N</i>,<i>N</i>-dipropylacrylamide, which contain from 0 to 95 mol % of <i>N</i>-(3-(diethylamino)propyl)-<i>N</i>-methyl-acrylamide units and have close molecular weights and the same degrees of polymerization (170 ± 10) are studied by the methods of potentiometric titration, light scattering, turbidimetry, refractometry, and viscometry. The samples are synthesized by the interaction of poly(acryloyl chloride) with <i>N</i>,<i>N</i>-diethyl-<i>N</i> ′-methyl-1,3-propanediamine and dipropylamine. The aqueous solutions are investigated in the concentration range from 0.0001 to 0.0350 g/cm<sup>3</sup> and in pH range from 7.0 to 13.0. Temperature dependences of optical transmission <i>I</i>*, scattered light intensity <i>I</i>, and hydrodynamic sizes of scattering objects are obtained. Phase separation temperatures are determined. The results obtained are comparable with the data available for the previously studied copolymers but containing <i>N</i>-(3-(diethylamino)propyl)-<i>N</i>-methylacrylamide and <i>N</i>,<i>N</i>–diethyl-acrylamide units. It is shown that the structural phase transition and the characteristics of aqueous solutions for the compared copolymers depend on the structure of the (co)polymers and their composition.</p>\",\"PeriodicalId\":738,\"journal\":{\"name\":\"Polymer Science, Series A\",\"volume\":\"65 6\",\"pages\":\"637 - 644\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2024-02-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Science, Series A\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0965545X24600042\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series A","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S0965545X24600042","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Thermo- and pH-Sensitive Copolymers of N-(3-(Diethylamino)Propyl)-N-methylacrylamide and N,N-Dipropylacrylamide
Buffer solutions of random (co)polymers of N-(3-(diethylamino)propyl)-N-methylacrylamide and N,N-dipropylacrylamide, which contain from 0 to 95 mol % of N-(3-(diethylamino)propyl)-N-methyl-acrylamide units and have close molecular weights and the same degrees of polymerization (170 ± 10) are studied by the methods of potentiometric titration, light scattering, turbidimetry, refractometry, and viscometry. The samples are synthesized by the interaction of poly(acryloyl chloride) with N,N-diethyl-N ′-methyl-1,3-propanediamine and dipropylamine. The aqueous solutions are investigated in the concentration range from 0.0001 to 0.0350 g/cm3 and in pH range from 7.0 to 13.0. Temperature dependences of optical transmission I*, scattered light intensity I, and hydrodynamic sizes of scattering objects are obtained. Phase separation temperatures are determined. The results obtained are comparable with the data available for the previously studied copolymers but containing N-(3-(diethylamino)propyl)-N-methylacrylamide and N,N–diethyl-acrylamide units. It is shown that the structural phase transition and the characteristics of aqueous solutions for the compared copolymers depend on the structure of the (co)polymers and their composition.
期刊介绍:
Polymer Science, Series A is a journal published in collaboration with the Russian Academy of Sciences. Series A includes experimental and theoretical papers and reviews devoted to physicochemical studies of the structure and properties of polymers (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed. Online submission via Internet to the Series A, B, and C is available at http://polymsci.ru.