基于噻唑-4-甲酰肼的新型含硫激光敏感原爆物

IF 3.3 Q2 CHEMISTRY, MULTIDISCIPLINARY
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引用次数: 0

摘要

本研究有效合成了噻唑-4-甲酰肼(SZCA)及其离子盐 SZCA-HClO4,以及高能络合物 Cu(SZCA)2(ClO4)2(ECC-1)。通过元素分析、红外光谱、13C NMR 光谱和热稳定性分析,对新化合物 SZCA、SZCA-HClO4 和 ECC-1 进行了全面表征。氧弹量热法测量了 ECC-1 的燃烧热,并分别用 Kamlet-Jacobs 公式和 EXPLO5 预测了其引爆性能。采用 BAM 法测试了 ECC-1 的机械敏感性。特别是,我们通过铅板破坏实验和激光起爆实验全面评估了 ECC-1 的起爆能力。结果表明,ECC-1 的分解温度为 236 ℃,具有可接受的机械灵敏度(冲击灵敏度:3.4 J,摩擦灵敏度:4 N)和良好的起爆性能(D:6.6 km s-1,P:21.3 GPa)。单脉冲激光(λ:808 nm,P:20 W,t:3 ms)可触发 ECC-1,并成功引爆下一个装药,如 RDX 和 CL-20。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A new sulfur-containing laser-sensitive primary explosive based on thiazole-4-carbohydrazide

A new sulfur-containing laser-sensitive primary explosive based on thiazole-4-carbohydrazide
This study effectively synthesized thiazole-4-carbohydrazide (SZCA) and its ionic salt SZCA·HClO4 and energetic complex Cu(SZCA)2(ClO4)2 (ECC-1). The new compound SZCA, SZCA·HClO4 and ECC-1 were fully characterized through elemental analysis, infrared spectroscopy, 13C NMR spectroscopy and thermal stability analysis. The combustion heat of ECC-1 was measured by oxygen bomb calorimetry, and its detonation performance was predicted by Kamlet-Jacobs formula and EXPLO5, respectively. The mechanical sensitivity of ECC-1 was tested using BAM method. In particular, we comprehensively evaluated the initiation ability of ECC-1 through lead plate destruction experiment and laser initiation experiment. The results show that ECC-1 have a decomposition temperature of 236 °C, exhibits acceptable mechanical sensitivity (impact sensitivity: 3.4 J, friction sensitivity: 4 N), and decent detonation properties (D: 6.6 km s−1, P: 21.3 GPa). And ECC-1 could be initiated by a single-pulse laser (λ: 808 nm, P: 20 W, t: 3 ms), and successfully detonated the next charge, such as RDX and CL-20.
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来源期刊
Energetic Materials Frontiers
Energetic Materials Frontiers Materials Science-Materials Science (miscellaneous)
CiteScore
6.90
自引率
0.00%
发文量
42
审稿时长
12 weeks
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