{"title":"基于噻唑-4-甲酰肼的新型含硫激光敏感原爆物","authors":"","doi":"10.1016/j.enmf.2024.02.005","DOIUrl":null,"url":null,"abstract":"<div><div>This study effectively synthesized thiazole-4-carbohydrazide (SZCA) and its ionic salt SZCA·HClO<sub>4</sub> and energetic complex Cu(SZCA)<sub>2</sub>(ClO<sub>4</sub>)<sub>2</sub> (<strong>ECC-1</strong>). The new compound SZCA, SZCA·HClO<sub>4</sub> and <strong>ECC-1</strong> were fully characterized through elemental analysis, infrared spectroscopy, <sup>13</sup>C NMR spectroscopy and thermal stability analysis. The combustion heat of <strong>ECC-1</strong> was measured by oxygen bomb calorimetry, and its detonation performance was predicted by Kamlet-Jacobs formula and EXPLO5, respectively. The mechanical sensitivity of <strong>ECC-1</strong> was tested using BAM method. In particular, we comprehensively evaluated the initiation ability of <strong>ECC-1</strong> through lead plate destruction experiment and laser initiation experiment. The results show that <strong>ECC-1</strong> have a decomposition temperature of 236 °C, exhibits acceptable mechanical sensitivity (impact sensitivity: 3.4 J, friction sensitivity: 4 N), and decent detonation properties (<em>D</em>: 6.6 km s<sup>−1</sup>, <em>P</em>: 21.3 GPa). And <strong>ECC-1</strong> could be initiated by a single-pulse laser (λ: 808 nm, <em>P</em>: 20 W, <em>t</em>: 3 ms), and successfully detonated the next charge, such as RDX and CL-20.</div></div>","PeriodicalId":34595,"journal":{"name":"Energetic Materials Frontiers","volume":null,"pages":null},"PeriodicalIF":3.3000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A new sulfur-containing laser-sensitive primary explosive based on thiazole-4-carbohydrazide\",\"authors\":\"\",\"doi\":\"10.1016/j.enmf.2024.02.005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study effectively synthesized thiazole-4-carbohydrazide (SZCA) and its ionic salt SZCA·HClO<sub>4</sub> and energetic complex Cu(SZCA)<sub>2</sub>(ClO<sub>4</sub>)<sub>2</sub> (<strong>ECC-1</strong>). The new compound SZCA, SZCA·HClO<sub>4</sub> and <strong>ECC-1</strong> were fully characterized through elemental analysis, infrared spectroscopy, <sup>13</sup>C NMR spectroscopy and thermal stability analysis. The combustion heat of <strong>ECC-1</strong> was measured by oxygen bomb calorimetry, and its detonation performance was predicted by Kamlet-Jacobs formula and EXPLO5, respectively. The mechanical sensitivity of <strong>ECC-1</strong> was tested using BAM method. In particular, we comprehensively evaluated the initiation ability of <strong>ECC-1</strong> through lead plate destruction experiment and laser initiation experiment. The results show that <strong>ECC-1</strong> have a decomposition temperature of 236 °C, exhibits acceptable mechanical sensitivity (impact sensitivity: 3.4 J, friction sensitivity: 4 N), and decent detonation properties (<em>D</em>: 6.6 km s<sup>−1</sup>, <em>P</em>: 21.3 GPa). And <strong>ECC-1</strong> could be initiated by a single-pulse laser (λ: 808 nm, <em>P</em>: 20 W, <em>t</em>: 3 ms), and successfully detonated the next charge, such as RDX and CL-20.</div></div>\",\"PeriodicalId\":34595,\"journal\":{\"name\":\"Energetic Materials Frontiers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2024-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Energetic Materials Frontiers\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S266664722400006X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energetic Materials Frontiers","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S266664722400006X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A new sulfur-containing laser-sensitive primary explosive based on thiazole-4-carbohydrazide
This study effectively synthesized thiazole-4-carbohydrazide (SZCA) and its ionic salt SZCA·HClO4 and energetic complex Cu(SZCA)2(ClO4)2 (ECC-1). The new compound SZCA, SZCA·HClO4 and ECC-1 were fully characterized through elemental analysis, infrared spectroscopy, 13C NMR spectroscopy and thermal stability analysis. The combustion heat of ECC-1 was measured by oxygen bomb calorimetry, and its detonation performance was predicted by Kamlet-Jacobs formula and EXPLO5, respectively. The mechanical sensitivity of ECC-1 was tested using BAM method. In particular, we comprehensively evaluated the initiation ability of ECC-1 through lead plate destruction experiment and laser initiation experiment. The results show that ECC-1 have a decomposition temperature of 236 °C, exhibits acceptable mechanical sensitivity (impact sensitivity: 3.4 J, friction sensitivity: 4 N), and decent detonation properties (D: 6.6 km s−1, P: 21.3 GPa). And ECC-1 could be initiated by a single-pulse laser (λ: 808 nm, P: 20 W, t: 3 ms), and successfully detonated the next charge, such as RDX and CL-20.