Cr2O3-Mn2O3着色剂体系对R2O-PbO-SiO2玻璃光谱特性的影响

D. V. Petrov, L. L. Bragina
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引用次数: 0

摘要

本文的重点是探索在波长为 1 060 纳米的红外光谱范围内具有高透过率的光学玻璃,同时在紫外线和可见光谱范围内显示出完全吸收。本文分析了在红外光谱范围内具有必要透射率的玻璃的现状,并考虑了它们固有的优势和局限性。在此背景下,一种含有 Cr2O3-Mn2O3 着色剂的 R2O-PbO-SiO2 玻璃系统成为本研究的主题。研究全面评估了这种着色剂体系对玻璃光谱特性的影响,同时考虑了氧化铁的潜在不利影响。研究发现,在玻璃熔化的冷却阶段使用气体加热会破坏玻璃的光谱均匀性,最终导致产品缺陷。在玻璃浇注前采用无气体降温方法(惯性冷却过程)为生产高质量产品创造了有利环境。从实验室测试中获得了玻璃样品,并将研究出的玻璃投入批量生产。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The influence of the Cr2O3–Mn2O3 colorants system on the spectral characteristics of R2O–PbO–SiO2 glasses

The influence of the Cr2O3–Mn2O3 colorants system on the spectral characteristics of R2O–PbO–SiO2 glasses

The influence of the Cr2O3–Mn2O3 colorants system on the spectral characteristics of R2O–PbO–SiO2 glasses

The focus of this paper centers on an exploration of optical glasses with high transmittance within the infrared spectrum at wavelength of 1 060 nm, while concurrently demonstrating full absorption within the ultraviolet and visible spectral ranges. The paper analyzes the present state of glasses demonstrating necessary transmittance at IR range, considering their inherent strengths and limitations. In this context, an R2O–PbO–SiO2 glass system with Cr2O3–Mn2O3 colorants system emerges as the subject of this research. Research was conducted to comprehensively assess the impact of this colorant system on the glass spectral characteristics, while considering the potentially detrimental influence of FeO.

The principles underlying the industrial production of these glasses are systematically elucidated and presented. It was discovered that using gas heating during the cooling phase of glass melting resulted in the disruption of the spectral homogeneity of the glass, ultimately leading to defective product outcomes. Implementing the methodology of gasless temperature reduction (inertial cooling process) before glass pouring has created a favorable environment for producing high-quality items. Glass samples from the laboratory tests were obtained, and the researched glass was integrated into serial production.

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