B. Avinash , C.R. Ravikumar , N. Basavaraju , Buzuayehu Abebe , T. Naveen Kumar , S.N. Manjula , H.C. Ananda Murthy
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引用次数: 0
摘要
以芦荟乳胶提取物(Avle)为燃料,采用生物燃烧法制备纳米氧化锌(ZnO)。XRD方法证实了ZnO的纳米晶性质和物相。利用Kubelka-Monk (K-M)函数对ZnO的DRS-UV-vis光谱进行分析,结果表明ZnO的带隙为2.79 eV。当用于评价氧化锌的光降解能力时,发现酸性红-88 (AR-88)染料在500 nm处被激活。在紫外线照射120分钟后,AR-88染料的光降解率降低了75.8%。采用ZnO纳米粒子增强的碳糊电极在1 M KOH溶液中检测扑热息痛和d -葡萄糖。循环伏安法的结果表明ZnO纳米粒子具有优异的电化学性能。ZnO电极材料的质子扩散系数为9.30 × 10−5cm2s−1。根据其电化学行为,ZnO是感应化学物质如扑热息痛和葡萄糖的良好电极催化剂。
Facile green synthesis of zinc oxide nanoparticles: Its photocatalytic and electrochemical sensor for the determination of paracetamol and D-glucose
The nanocrystalline zinc oxide (ZnO) was produced utilizing a bio-combustion process with Aloe vera latex extract (Avle) as the fuel. The XRD method proved the nanocrystalline nature and phase of ZnO. The Kubelka-Monk (K-M) function was used to analyze the DRS-UV-vis spectrum, and the results revealed that ZnO has a band gap of 2.79 eV. When utilized to evaluate the photo-degradation capabilities of ZnO, the acid red-88 (AR-88) dye was found to be activated at 500 nm. After 120 min of exposure to UV radiation, the AR-88 dye's photodegradation rate reduced its hue by up to 75.8%. A carbon paste electrode that had been enhanced with ZnO nanoparticles (NPs) was used to detect paracetamol and D-glucose in a 1 M KOH solution. The result of the cyclic voltammetry points to the excellent electrochemical qualities of ZnO NPs. ZnO electrode material was found to have a proton diffusion coefficient of 9.30 × 10−5cm2s−1. ZnO is a decent electrode catalyst for sensing chemicals like paracetamol and glucose, according to its electrochemical behavior.