含二元碳纳米填料的聚丙烯组合物的制备与性能

IF 1 4区 化学 Q4 POLYMER SCIENCE
O. M. Palaznik, P. M. Nedorezova, V. G. Shevchenko, V. G. Krasheninnikov, A. N. Klyamkina, T. V. Monakhova, A. A. Gulin, A. A. Arbuzov
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引用次数: 0

摘要

摘要利用甲基铝氧烷活化的均相异茂金属催化剂 rac-Me2Si(2-Me-4-PhInd)2ZrCl2,通过原位聚合合成了基于聚丙烯和二元碳纳米填料(石墨烯颗粒和单壁碳纳米管)的复合材料。二元碳纳米填料的使用提高了热稳定性和抗热氧化降解能力,并影响了合成材料的反射率和其他电学特性。研究表明,二元纳米填料可对聚丙烯的热氧化产生协同效应。在石墨烯纳米片中引入即使是少量的单壁碳纳米管,也会显著降低所得复合材料的反射系数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Preparation and Properties of Polypropylene Compositions with Binary Carbon Nanofillers

Preparation and Properties of Polypropylene Compositions with Binary Carbon Nanofillers

Preparation and Properties of Polypropylene Compositions with Binary Carbon Nanofillers

Composites based on polypropylene and binary carbon nanofillers (graphene particles and single-walled carbon nanotubes) have been synthesized by in situ polymerization using the homogeneous isospecific metallocene catalyst rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated by methylaluminoxane. The use of binary carbon nanofillers increases thermal stability and resistance to thermo-oxidative degradation and affects the reflectance and other electrical characteristics of synthesized materials. It has been shown that the binary nanofillers can have a synergistic effect on the thermal oxidation of polypropylene. The introduction of even a small amount of single-walled carbon nanotubes into graphene nanoplatelets significantly reduces the reflection coefficient of the resulting composite materials.

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来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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