工业相关化合物中二氧化碳的电化学价值化和掺入比较概述

EES catalysis Pub Date : 2024-02-16 DOI:10.1039/D4EY00005F
Jef R. Vanhoof, Sander Spittaels and Dirk E. De Vos
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引用次数: 0

摘要

气候变化是一项严峻的全球性挑战,需要采取紧急行动减少温室气体排放,包括二氧化碳(CO2)。在通过开发新的生产工艺努力减少排放的同时,对已经过量产生的二氧化碳进行可持续利用的研究也至关重要。电化学二氧化碳还原反应(eCO2RR)是将二氧化碳转化为有价值的基础化学品和燃料的一种极具前景的多功能方法,可有效实现化工行业的去碳化。该领域的新方法和电催化剂正得到越来越多的研究,强调向更具可持续性的未来过渡的必要性。在本综述中,我们将重点关注 eCO2RR 与有机或无机反应物的结合,以获得关键的工业化合物,如羧酸、脲和碳酸二甲酯。我们概述了目前设想化合物的工业合成方法,从而提供了更广泛的背景。为了便于快速比较,我们用表格总结了近期的工作,同时更详细地介绍了在可持续性和适用性方面的创新和改进。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A comparative overview of the electrochemical valorization and incorporation of CO2 in industrially relevant compounds

A comparative overview of the electrochemical valorization and incorporation of CO2 in industrially relevant compounds

Climate change is a critical global challenge that requires urgent action to reduce greenhouse gas emissions, including carbon dioxide (CO2). While essential efforts are being made to reduce emissions by developing new manufacturing processes, it is also crucial to scrutinize sustainable uses for the CO2 that is already produced in excess. The electrochemical CO2 reduction reaction (eCO2RR) is a highly promising and versatile approach for converting CO2 into valuable base chemicals and fuels, effectively decarbonizing the chemical industry. New methodologies and electrocatalysts in this area are increasingly being investigated, emphasizing the necessary transition to a more sustainable future. In this review, we focus on the eCO2RR coupled with incorporation in organic or inorganic reactants towards key industrial compounds such as carboxylic acids, ureas and dimethyl carbonate. We provide a broader context by outlining the current industrial synthesis methods of the envisioned compounds. Recent work is summarized in tables for quick comparison while innovations and improvements regarding sustainability and applicability are addressed in more detail.

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