邻氧氮杂环丁烷的原位同分异构。(E)-1-(((吡啶-3-基甲基)亚氨基)甲基)萘-2-醇的晶体结构

IF 0.6 4区材料科学 Q4 CRYSTALLOGRAPHY

Crystallography Reports Pub Date : 2024-02-06 DOI:10.1134/s1063774523600382

V. S. Sergienko, V. L. Abramenko, M. D. Surazhskaya, A. V. Churakov

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引用次数: 0

摘要

摘要合成了(Е)-1-(((吡啶-3-基甲基)亚氨基)甲基)萘-2-醇（H2L1），并通过红外光谱和单晶 X 射线衍射分析对其进行了表征。在 H2L1 的结构中，双环萘环系统 С10Н6 和吡啶环（Ру）通过 HC-N-CH2 人字形三单位链连接。我们将 H2L1 分子的结构与已知的含有两个六元环（两个 Ph 环或 Ph 环和 Ру环）的化合物的结构进行了比较，这些化合物由之字形 n 单元链连接（n = 3、4、6、7）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Prototropic Tautomerism of o-Oxyazomethines. Crystal Structure of (E)-1-(((Pyridin-3-ylmethyl)iminio)methyl)naphthalen-2-olate

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Prototropic Tautomerism of o-Oxyazomethines. Crystal Structure of (E)-1-(((Pyridin-3-ylmethyl)iminio)methyl)naphthalen-2-olate

Abstract

(Е)-1-(((Pyridin-3-ylmethyl)iminio)methyl)naphthalen-2-olate (H₂L¹) was synthesized and characterized by IR spectroscopy and single-crystal X-ray diffraction analysis. In the structure of H₂L¹, the bicyclic naphthalene ring system С₁₀Н₆ and the pyridine ring (Ру) are linked by the zigzag three-unit chain HC–N–CH₂. The structure of the H₂L¹ molecule was compared with the known structures of the compounds containing two six-membered rings (two Ph rings or Ph and Ру rings) linked by zigzag n-unit chains (n = 3, 4, 6, 7).

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来源期刊

Crystallography Reports 化学-晶体学

CiteScore

1.10

自引率

28.60%

发文量

审稿时长

4-8 weeks

期刊介绍： Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.