静态气体背景信号对电子-分子碰撞实验中动量成像的影响

IF 1.6 3区 化学 Q3 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
Sukanta Das, Suvasis Swain , Krishnendu Gope , Vishvesh Tadsare, Vaibhav S. Prabhudesai
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引用次数: 0

摘要

速度切片成像技术彻底改变了一般的带电粒子-分子相互作用研究,特别是电子-分子相互作用研究。光谱仪中通常使用多个静电透镜组件来分辨低动能碎片。在以喷出分子束为目标的交叉光束实验中,背景气体会形成一个强大的扩展离子源,带电粒子束在此被用作射弹而无需聚焦。当我们试图将其放大到超过一定尺寸时,这种扩展源会在动量图像上产生伪影。在此,我们以低能量电子分子碰撞为例,系统地研究了这一现象对动量成像的影响,并介绍了通过适当放大背景减除来解决这一问题的方法。此外,我们还证明了超音速分子束目标有助于通过减少背景信号来最大限度地减少图像放大中的这些伪影。这些系统性的发现可能会为涉及电子撞击、离子撞击的低动能释放过程的研究带来有价值的启示,也可能会为具有大相互作用体积的合并光束实验带来有价值的启示,因为在这些实验中,高放大倍率是必不可少的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Effect of static gas background signal on momentum imaging in electron-molecule collision experiment

Effect of static gas background signal on momentum imaging in electron-molecule collision experiment

The Velocity Slice Imaging technique has revolutionized charged particle-molecule interaction studies in general and electron-molecule interaction studies in particular. Multiple electrostatic lens assemblies are often used in spectrometers for resolving low kinetic energy fragments. In a crossed-beam experiment with an effusive molecular beam as a target, the background gas forms a strong extended source of ions where the charged particle beam is used as a projectile without focusing. This extended source creates artefacts on the momentum images as we try to magnify them beyond a certain size. Here, we present a systematic study of this effect on momentum imaging in the low-energy-electron molecule collisions as an example and the solutions to address this issue by background subtraction with suitable magnification. Additionally, we demonstrated that a supersonic molecular beam target helps minimize these artefacts in the image magnification by reducing the background signal. These systematic findings may bring valuable insight into the investigation of low kinetic energy release processes involving electron impact, ion impact, and merge beam experiments with large interaction volumes where high magnification is essential.

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来源期刊
CiteScore
3.60
自引率
5.60%
发文量
145
审稿时长
71 days
期刊介绍: The journal invites papers that advance the field of mass spectrometry by exploring fundamental aspects of ion processes using both the experimental and theoretical approaches, developing new instrumentation and experimental strategies for chemical analysis using mass spectrometry, developing new computational strategies for data interpretation and integration, reporting new applications of mass spectrometry and hyphenated techniques in biology, chemistry, geology, and physics. Papers, in which standard mass spectrometry techniques are used for analysis will not be considered. IJMS publishes full-length articles, short communications, reviews, and feature articles including young scientist features.
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