电催化硝酸盐还原成氨的铜基催化剂:基本原理和最新进展

EES catalysis Pub Date : 2024-02-05 DOI:10.1039/D4EY00002A
Kouer Zhang, Yun Liu, Zhefei Pan, Qing Xia, Xiaoyu Huo, Oladapo Christopher Esan, Xiao Zhang and Liang An
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引用次数: 0

摘要

电催化硝酸盐还原法被认为是一种很有前途的绿色氨生产技术,它可以在环境条件下利用可再生电力将废水中的有害硝酸盐转化为有价值的氨。开发先进的电催化剂对于提高该工艺的氨生产效率至关重要。近年来,铜基催化剂因其快速的还原反应动力学、较强的导电性和对氢进化反应的抑制作用,在硝酸盐还原制氨过程中得到了广泛的研究。同时,为了理解铜基催化剂有利特性背后的理论,人们对其反应机理、计算和实验方法进行了广泛的讨论。在本综述中,我们将重点讨论铜基催化剂,旨在深入探讨硝酸盐还原成氨的中间产物和产物的最新发展、反应机理和最先进的分析方法。此外,还介绍了未来展望和仍然面临的挑战,为从实验探索到实际应用的进展提供指导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Cu-based catalysts for electrocatalytic nitrate reduction to ammonia: fundamentals and recent advances

Cu-based catalysts for electrocatalytic nitrate reduction to ammonia: fundamentals and recent advances

Electrocatalytic nitrate reduction has been identified as a promising technology for green ammonia production, allowing the conversion of harmful nitrate from wastewater into valuable ammonia using renewable electricity under ambient conditions. Developing advanced electrocatalysts is of paramount significance for improving the ammonia production efficiency in this process. Recently, Cu-based catalysts have been widely investigated in ammonia production via nitrate reduction due to their rapid reduction reaction kinetics, strong electrical conductivity, and ability to inhibit the hydrogen evolution reaction. Meanwhile, the reaction mechanism and computational and experimental methods have been extensively discussed to understand the theory behind the favourable properties of Cu-based catalysts. In this review, we focus on Cu-based catalysts, aiming to provide insights into the latest developments, reaction mechanisms, and state-of-the-art analysis methods for intermediates and products of nitrate reduction to ammonia. Future outlooks and remaining challenges are presented to provide guidance for advancing from experimental explorations to practical applications.

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