Jinghua Zhao, Ming Zhang, Yongxing Guo, Wei Liu, Yi Li, Yonggang Yang
{"title":"使用胆甾液晶墨水制备彩色胆甾液晶聚合物网络图案","authors":"Jinghua Zhao, Ming Zhang, Yongxing Guo, Wei Liu, Yi Li, Yonggang Yang","doi":"10.1016/j.giant.2024.100244","DOIUrl":null,"url":null,"abstract":"<div><p>Colorful cholesteric liquid crystal polymer network (CLCN) patterns can be applied for decoration and anti-counterfeiting. Herein, the CLC inks were prepared using an acrylate liquid crystal, chiral dopants and a photoinitiator. Full-color CLCN patterns were able to be printed out using only two CLC inks by changing their volume ratio. A structure with a gradient helical pitch was identified between different colors. For anti-counterfeiting, the color patterns composed of opposite-handed CLCNs were also printed. A helical-nonhelical-helical structure was identified at the interface. In addition, CLCN patterns with a grating structure were also prepared. The results shown here not only give us a better understanding the cholesteric structure, but also lay the foundations for the applications of CLCN patterns in the fields of decoration and anti-counterfeiting.</p></div>","PeriodicalId":34151,"journal":{"name":"GIANT","volume":"17 ","pages":"Article 100244"},"PeriodicalIF":5.4000,"publicationDate":"2024-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666542524000092/pdfft?md5=9ba0f8a85086eb4bb36127079ca33bb2&pid=1-s2.0-S2666542524000092-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Colorful cholesteric liquid crystal polymer network patterns prepared using cholesteric liquid crystal inks\",\"authors\":\"Jinghua Zhao, Ming Zhang, Yongxing Guo, Wei Liu, Yi Li, Yonggang Yang\",\"doi\":\"10.1016/j.giant.2024.100244\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Colorful cholesteric liquid crystal polymer network (CLCN) patterns can be applied for decoration and anti-counterfeiting. Herein, the CLC inks were prepared using an acrylate liquid crystal, chiral dopants and a photoinitiator. Full-color CLCN patterns were able to be printed out using only two CLC inks by changing their volume ratio. A structure with a gradient helical pitch was identified between different colors. For anti-counterfeiting, the color patterns composed of opposite-handed CLCNs were also printed. A helical-nonhelical-helical structure was identified at the interface. In addition, CLCN patterns with a grating structure were also prepared. The results shown here not only give us a better understanding the cholesteric structure, but also lay the foundations for the applications of CLCN patterns in the fields of decoration and anti-counterfeiting.</p></div>\",\"PeriodicalId\":34151,\"journal\":{\"name\":\"GIANT\",\"volume\":\"17 \",\"pages\":\"Article 100244\"},\"PeriodicalIF\":5.4000,\"publicationDate\":\"2024-02-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2666542524000092/pdfft?md5=9ba0f8a85086eb4bb36127079ca33bb2&pid=1-s2.0-S2666542524000092-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"GIANT\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666542524000092\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"GIANT","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666542524000092","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Colorful cholesteric liquid crystal polymer network (CLCN) patterns can be applied for decoration and anti-counterfeiting. Herein, the CLC inks were prepared using an acrylate liquid crystal, chiral dopants and a photoinitiator. Full-color CLCN patterns were able to be printed out using only two CLC inks by changing their volume ratio. A structure with a gradient helical pitch was identified between different colors. For anti-counterfeiting, the color patterns composed of opposite-handed CLCNs were also printed. A helical-nonhelical-helical structure was identified at the interface. In addition, CLCN patterns with a grating structure were also prepared. The results shown here not only give us a better understanding the cholesteric structure, but also lay the foundations for the applications of CLCN patterns in the fields of decoration and anti-counterfeiting.
期刊介绍:
Giant is an interdisciplinary title focusing on fundamental and applied macromolecular science spanning all chemistry, physics, biology, and materials aspects of the field in the broadest sense. Key areas covered include macromolecular chemistry, supramolecular assembly, multiscale and multifunctional materials, organic-inorganic hybrid materials, biophysics, biomimetics and surface science. Core topics range from developments in synthesis, characterisation and assembly towards creating uniformly sized precision macromolecules with tailored properties, to the design and assembly of nanostructured materials in multiple dimensions, and further to the study of smart or living designer materials with tuneable multiscale properties.