Darío Puchán Sánchez, Dr. Pierre Josse, Dr. Monika G. Mutovska, Benjamin Siegler, Dr. Magali Allain, Korentin Morice, Dr. Philippe Blanchard, Prof. Frédéric Gohier, Prof. Tangui Le Bahers, Prof. Cyrille Monnereau, Prof. Yulian Zagranyarski, Prof. Dominik Lungerich, Prof. Dr. Clément Cabanetos
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Cover Feature: Radical-Formation Management: Towards Aza-Analogues of the Benzothioxanthene Imide (ChemistryEurope 1/2024)
Subtle chemical modifications of an intermediate can have significant impacts, since they usually considered to control the reactivity. In their Research Article, J. Zagranyarski, D. Lungerich, C. Cabanetos, and co-workers report the preparation of aza derivatives of the benzothixanthene imide. The intramolecular radical cyclization can be controlled by means of a simple methylation to either afford the thermodynamically favored six-membered or its kinetically favored five-membered ring regioisomers, exhibiting significant photophysical properties.
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