{"title":"通过添加 Mg2+ 实现双离子载流子存储,打造高能量、长寿命的锌-离子混合电容器","authors":"Junjie Zhang, Xiang Wu","doi":"10.1007/s12613-023-2724-4","DOIUrl":null,"url":null,"abstract":"<p>Cation additives can efficiently enhance the total electrochemical capabilities of zinc-ion hybrid capacitors (ZHCs). However, their energy storage mechanisms in zinc-based systems are still under debate. Herein, we modulate the electrolyte and achieve dual-ion storage by adding magnesium ions. And we assemble several Zn//activated carbon devices with different electrolyte concentrations and investigate their electrochemical reaction dynamic behaviors. The zinc-ion capacitor with Mg<sup>2+</sup> mixed solution delivers 82 mAh·g<sup>−1</sup> capacity at 1 A·g<sup>−1</sup> and maintains 91% of the original capacitance after 10000 cycling. It is superior to the other assembled zinc-ion devices in single-component electrolytes. The finding demonstrates that the double-ion storage mechanism enables the superior rate performance and long cycle lifetime of ZHCs.</p>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"10 1","pages":""},"PeriodicalIF":5.6000,"publicationDate":"2024-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dual-ion carrier storage through Mg2+ addition for high-energy and long-life zinc-ion hybrid capacitor\",\"authors\":\"Junjie Zhang, Xiang Wu\",\"doi\":\"10.1007/s12613-023-2724-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Cation additives can efficiently enhance the total electrochemical capabilities of zinc-ion hybrid capacitors (ZHCs). However, their energy storage mechanisms in zinc-based systems are still under debate. Herein, we modulate the electrolyte and achieve dual-ion storage by adding magnesium ions. And we assemble several Zn//activated carbon devices with different electrolyte concentrations and investigate their electrochemical reaction dynamic behaviors. The zinc-ion capacitor with Mg<sup>2+</sup> mixed solution delivers 82 mAh·g<sup>−1</sup> capacity at 1 A·g<sup>−1</sup> and maintains 91% of the original capacitance after 10000 cycling. It is superior to the other assembled zinc-ion devices in single-component electrolytes. The finding demonstrates that the double-ion storage mechanism enables the superior rate performance and long cycle lifetime of ZHCs.</p>\",\"PeriodicalId\":14030,\"journal\":{\"name\":\"International Journal of Minerals, Metallurgy, and Materials\",\"volume\":\"10 1\",\"pages\":\"\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-01-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Minerals, Metallurgy, and Materials\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1007/s12613-023-2724-4\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Minerals, Metallurgy, and Materials","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1007/s12613-023-2724-4","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Dual-ion carrier storage through Mg2+ addition for high-energy and long-life zinc-ion hybrid capacitor
Cation additives can efficiently enhance the total electrochemical capabilities of zinc-ion hybrid capacitors (ZHCs). However, their energy storage mechanisms in zinc-based systems are still under debate. Herein, we modulate the electrolyte and achieve dual-ion storage by adding magnesium ions. And we assemble several Zn//activated carbon devices with different electrolyte concentrations and investigate their electrochemical reaction dynamic behaviors. The zinc-ion capacitor with Mg2+ mixed solution delivers 82 mAh·g−1 capacity at 1 A·g−1 and maintains 91% of the original capacitance after 10000 cycling. It is superior to the other assembled zinc-ion devices in single-component electrolytes. The finding demonstrates that the double-ion storage mechanism enables the superior rate performance and long cycle lifetime of ZHCs.
期刊介绍:
International Journal of Minerals, Metallurgy and Materials (Formerly known as Journal of University of Science and Technology Beijing, Mineral, Metallurgy, Material) provides an international medium for the publication of theoretical and experimental studies related to the fields of Minerals, Metallurgy and Materials. Papers dealing with minerals processing, mining, mine safety, environmental pollution and protection of mines, process metallurgy, metallurgical physical chemistry, structure and physical properties of materials, corrosion and resistance of materials, are viewed as suitable for publication.