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铂(ƞ3-X1C1X2)(PL)（X1,2 = N 或 S）、铂(ƞ3-X1N1Y1)(PL)（X, Y = O, C; C, S; 或 O, S）和铂(ƞ3-S1B1S2)(PL)中的可变异戟配体，衍生物 - 结构方面的问题

IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR
Reviews in Inorganic Chemistry Pub Date : 2024-01-19 DOI:10.1515/revic-2023-0029
Milan Melník, Dominika Žigrayová, Veronika Mikušová, Peter Mikuš
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These complexes crystallized in three crystal classes: monoclinic (8 examples), triclinic (8 examples) and orthorhombic (1 example). The heterotridentate ligands creates 5 + 5-membered metallocyclic rings (most common) and 5 + 6-membered. The heterotridentate ligands with monodentate P ligands build up a distorted square-planar geometry about Pt(II) atoms. The Pt–L and L–Pt–L were analyzed. The <jats:italic>τ</jats:italic> <jats:sub>4</jats:sub> parameter which indicate a degree of distortion growing in the sentence: 0.057 Pt(ƞ<jats:sup>3</jats:sup>-O<jats:sup>1</jats:sup>N<jats:sup>1</jats:sup>S<jats:sup>1</jats:sup>)(PL) &lt; 0.066 Pt(ƞ<jats:sup>3</jats:sup>-S<jats:sup>1</jats:sup>C<jats:sup>1</jats:sup>S<jats:sup>2</jats:sup>)(PL) &lt; 0.149 Pt(ƞ<jats:sup>3</jats:sup>-S<jats:sup>1</jats:sup>S<jats:sup>2</jats:sup>O<jats:sup>1</jats:sup>)(PL) &lt; 0.158 Pt(ƞ<jats:sup>3</jats:sup>-O<jats:sup>1</jats:sup>N<jats:sup>1</jats:sup>C<jats:sup>1</jats:sup>)(PL) &lt; 0.160 Pt(ƞ<jats:sup>3</jats:sup>-C<jats:sup>1</jats:sup>N<jats:sup>1</jats:sup>S<jats:sup>1</jats:sup>)(PL) &lt; 0.162 Pt(ƞ<jats:sup>3</jats:sup>-S<jats:sup>1</jats:sup>B<jats:sup>1</jats:sup>S<jats:sup>2</jats:sup>)(PL) &lt; 0.165 Pt(ƞ<jats:sup>3</jats:sup>-N<jats:sup>1</jats:sup>C<jats:sup>1</jats:sup>N<jats:sup>2</jats:sup>)(PL).","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"35 1","pages":""},"PeriodicalIF":4.1000,"publicationDate":"2024-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Variable heterotridentate ligands in Pt(ƞ3-X1C1X2)(PL) (X1,2 = N or S), Pt(ƞ3-X1N1Y1)(PL) (X, Y = O, C; C, S; or O, S) and Pt(ƞ3-S1B1S2)(PL), derivatives – structural aspects\",\"authors\":\"Milan Melník, Dominika Žigrayová, Veronika Mikušová, Peter Mikuš\",\"doi\":\"10.1515/revic-2023-0029\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This review covers 17 Pt(II) complexes of the compositions: Pt(ƞ<jats:sup>3</jats:sup>-N<jats:sup>1</jats:sup>C<jats:sup>1</jats:sup>N<jats:sup>2</jats:sup>)(PL), Pt(ƞ<jats:sup>3</jats:sup>-S<jats:sup>1</jats:sup>C<jats:sup>1</jats:sup>S<jats:sup>2</jats:sup>)(PL), Pt(ƞ<jats:sup>3</jats:sup>-S<jats:sup>1</jats:sup>B<jats:sup>1</jats:sup>S<jats:sup>2</jats:sup>)(PL), Pt(ƞ<jats:sup>3</jats:sup>-S<jats:sup>1</jats:sup>S<jats:sup>2</jats:sup>O<jats:sup>1</jats:sup>)(PL), Pt(ƞ<jats:sup>3</jats:sup>-O<jats:sup>1</jats:sup>N<jats:sup>1</jats:sup>C<jats:sup>1</jats:sup>)(PL), Pt(ƞ<jats:sup>3</jats:sup>-O<jats:sup>1</jats:sup>N<jats:sup>1</jats:sup>S<jats:sup>1</jats:sup>)(PL) and Pt(ƞ<jats:sup>3</jats:sup>-C<jats:sup>1</jats:sup>N<jats:sup>1</jats:sup>S<jats:sup>1</jats:sup>)(PL). 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The <jats:italic>τ</jats:italic> <jats:sub>4</jats:sub> parameter which indicate a degree of distortion growing in the sentence: 0.057 Pt(ƞ<jats:sup>3</jats:sup>-O<jats:sup>1</jats:sup>N<jats:sup>1</jats:sup>S<jats:sup>1</jats:sup>)(PL) &lt; 0.066 Pt(ƞ<jats:sup>3</jats:sup>-S<jats:sup>1</jats:sup>C<jats:sup>1</jats:sup>S<jats:sup>2</jats:sup>)(PL) &lt; 0.149 Pt(ƞ<jats:sup>3</jats:sup>-S<jats:sup>1</jats:sup>S<jats:sup>2</jats:sup>O<jats:sup>1</jats:sup>)(PL) &lt; 0.158 Pt(ƞ<jats:sup>3</jats:sup>-O<jats:sup>1</jats:sup>N<jats:sup>1</jats:sup>C<jats:sup>1</jats:sup>)(PL) &lt; 0.160 Pt(ƞ<jats:sup>3</jats:sup>-C<jats:sup>1</jats:sup>N<jats:sup>1</jats:sup>S<jats:sup>1</jats:sup>)(PL) &lt; 0.162 Pt(ƞ<jats:sup>3</jats:sup>-S<jats:sup>1</jats:sup>B<jats:sup>1</jats:sup>S<jats:sup>2</jats:sup>)(PL) &lt; 0.165 Pt(ƞ<jats:sup>3</jats:sup>-N<jats:sup>1</jats:sup>C<jats:sup>1</jats:sup>N<jats:sup>2</jats:sup>)(PL).\",\"PeriodicalId\":21162,\"journal\":{\"name\":\"Reviews in Inorganic Chemistry\",\"volume\":\"35 1\",\"pages\":\"\"},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2024-01-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reviews in Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1515/revic-2023-0029\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reviews in Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/revic-2023-0029","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

摘要

本综述涉及 17 种铂(II)络合物的组成：Pt(ƞ3-N1C1N2)(PL)、Pt(ƞ3-S1C1S2)(PL)、Pt(ƞ3-S1B1S2)(PL)、Pt(ƞ3-S1S2O1)(PL)、Pt(ƞ3-O1N1C1)(PL)、Pt(ƞ3-O1N1S1)(PL) 和 Pt(ƞ3-C1N1S1)(PL)。这些配合物以三种晶体类别结晶：单斜（8 例）、三斜（8 例）和正交（1 例）。杂三齿配体形成了 5 + 5 元金属环（最常见）和 5 + 6 元金属环。带有单齿 P 配体的杂三叉配体会围绕铂（II）原子形成扭曲的方形平面几何。分析了 Pt-L 和 L-Pt-L。表示畸变程度的 τ 4 参数在句子中不断增加：0.057 Pt(ƞ3-O1N1S1)(PL) < 0.066 Pt(ƞ3-S1C1S2)(PL) < 0.149 Pt(ƞ3-S1S2O1)(PL) < 0.158 Pt(ƞ3-O1N1C1)(PL) < 0.160 Pt(ƞ3-C1N1S1)(PL) < 0.162 Pt(ƞ3-S1B1S2)(PL) < 0.165 Pt(ƞ3-N1C1N2)(PL).
本文章由计算机程序翻译，如有差异，请以英文原文为准。
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Variable heterotridentate ligands in Pt(ƞ3-X1C1X2)(PL) (X1,2 = N or S), Pt(ƞ3-X1N1Y1)(PL) (X, Y = O, C; C, S; or O, S) and Pt(ƞ3-S1B1S2)(PL), derivatives – structural aspects
This review covers 17 Pt(II) complexes of the compositions: Pt(ƞ3-N1C1N2)(PL), Pt(ƞ3-S1C1S2)(PL), Pt(ƞ3-S1B1S2)(PL), Pt(ƞ3-S1S2O1)(PL), Pt(ƞ3-O1N1C1)(PL), Pt(ƞ3-O1N1S1)(PL) and Pt(ƞ3-C1N1S1)(PL). These complexes crystallized in three crystal classes: monoclinic (8 examples), triclinic (8 examples) and orthorhombic (1 example). The heterotridentate ligands creates 5 + 5-membered metallocyclic rings (most common) and 5 + 6-membered. The heterotridentate ligands with monodentate P ligands build up a distorted square-planar geometry about Pt(II) atoms. The Pt–L and L–Pt–L were analyzed. The τ 4 parameter which indicate a degree of distortion growing in the sentence: 0.057 Pt(ƞ3-O1N1S1)(PL) < 0.066 Pt(ƞ3-S1C1S2)(PL) < 0.149 Pt(ƞ3-S1S2O1)(PL) < 0.158 Pt(ƞ3-O1N1C1)(PL) < 0.160 Pt(ƞ3-C1N1S1)(PL) < 0.162 Pt(ƞ3-S1B1S2)(PL) < 0.165 Pt(ƞ3-N1C1N2)(PL).
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来源期刊
Reviews in Inorganic Chemistry
Reviews in Inorganic Chemistry 化学-分析化学
CiteScore
7.30
自引率
4.90%
发文量
20
审稿时长
1 months
期刊介绍： Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process. Topics: -Main group chemistry- Transition metal chemistry- Coordination chemistry- Organometallic chemistry- Catalysis- Bioinorganic chemistry- Supramolecular chemistry- Ionic liquids
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