{"title":"利用基于类石墨氮化碳的系统对生物质成分进行光催化转化:综述","authors":"S. Ya. Kuchmiy","doi":"10.1007/s11237-024-09783-y","DOIUrl":null,"url":null,"abstract":"<p>The current state of research on photocatalytic reforming of organic substances of natural origin using graphite-like carbon nitride, namely its various morphological forms, products of modification by chemical agents, doped with metals and non-metals, nanocomposites with metals and other semiconductors, etc., is considered. Reactions that lead to molecular hydrogen evolution from aqueous solutions of electron-donating organic compounds (lignocellulose, saccharides, alcohols, aldehydes, and acids), processes of simultaneous production of H<sub>2</sub> and oxidation of biomass components with the formation of valuable organic substances, as well as reactions of a reduction of several aldehydes of natural origin are analyzed. Possible ways of further research in this photocatalysis branch are outlined.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":"59 4","pages":"231 - 259"},"PeriodicalIF":0.7000,"publicationDate":"2024-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photocatalytic Reforming of Biomass Components Using Systems Based on Graphite-Like Carbon Nitride: A Review\",\"authors\":\"S. Ya. Kuchmiy\",\"doi\":\"10.1007/s11237-024-09783-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The current state of research on photocatalytic reforming of organic substances of natural origin using graphite-like carbon nitride, namely its various morphological forms, products of modification by chemical agents, doped with metals and non-metals, nanocomposites with metals and other semiconductors, etc., is considered. Reactions that lead to molecular hydrogen evolution from aqueous solutions of electron-donating organic compounds (lignocellulose, saccharides, alcohols, aldehydes, and acids), processes of simultaneous production of H<sub>2</sub> and oxidation of biomass components with the formation of valuable organic substances, as well as reactions of a reduction of several aldehydes of natural origin are analyzed. Possible ways of further research in this photocatalysis branch are outlined.</p>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":\"59 4\",\"pages\":\"231 - 259\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2024-01-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-024-09783-y\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-024-09783-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Photocatalytic Reforming of Biomass Components Using Systems Based on Graphite-Like Carbon Nitride: A Review
The current state of research on photocatalytic reforming of organic substances of natural origin using graphite-like carbon nitride, namely its various morphological forms, products of modification by chemical agents, doped with metals and non-metals, nanocomposites with metals and other semiconductors, etc., is considered. Reactions that lead to molecular hydrogen evolution from aqueous solutions of electron-donating organic compounds (lignocellulose, saccharides, alcohols, aldehydes, and acids), processes of simultaneous production of H2 and oxidation of biomass components with the formation of valuable organic substances, as well as reactions of a reduction of several aldehydes of natural origin are analyzed. Possible ways of further research in this photocatalysis branch are outlined.
期刊介绍:
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.