电镀法制备的银薄膜的结构和微通道催化床性能

IF 3.8 3区 化学 Q2 CHEMISTRY, PHYSICAL
Catalysts Pub Date : 2024-01-05 DOI:10.3390/catal14010039
Yong Yang, Y. Ye, Rui-qi Shen
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引用次数: 0

摘要

微通道中催化剂的形态对以过氧化氢为单位推进剂的微型/纳米卫星的轨道机动和网络应用起着至关重要的作用。本文设计并制作了一种微流控反应芯片,用于检测微通道催化床催化分解过氧化氢溶液的反应速率。此外,还使用恒流电镀法制备的银薄膜作为微通道催化剂的基底。结果表明,银薄膜的表面积与面积之比、银颗粒的平均粒径对催化分解反应速率有显著的正相关关系,而银薄膜的厚度、含银量和表面粗糙度对催化分解反应速率无显著影响。银薄膜微通道催化床的催化性能受电镀条件,即电镀温度(T)、时间(t)和电流(I)的影响很大。当电流(I)= 0.3 mA、时间(t)= 180 s、温度(T)= 60 ℃时,电镀法制备的银薄膜微通道催化床达到了催化分解过氧化氢溶液的最佳反应速率。这项研究为应用于微流控反应器的异相催化剂的设计和优化提供了最佳工艺参数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Structure and Microchannel Catalytic Bed Performance of Silver Thin Films Prepared by Electroplating
The morphology of catalysts in microchannels plays a crucial role in the orbital maneuvering and networking applications of micro/nano satellites using hydrogen peroxide as a unit propellant. In this paper, a microfluidic reaction chip was designed and fabricated to detect the reaction rate of the catalytic decomposition of hydrogen peroxide solution by a microchannel catalytic bed. In addition, a silver thin film prepared by constant-current electroplating was used as a substrate for the microchannel catalyst. The results show that the ratio of surface area to area of silver film and the average particle size of silver particles have a significant positive correlation on the reaction rate of catalytic decomposition, while the thickness, silver content, and surface roughness of the silver film have no significant effect on the reaction rate of catalytic decomposition. The catalytic performance of the microchannel catalytic bed of silver thin film is greatly influenced by the conditions of electroplating, namely, the electroplating temperature (T), time (t), and current (I). And when I = 0.3 mA, t = 180 s, and T = 60 °C, the microchannel catalytic bed of the silver film prepared by electroplating reaches the optimal reaction rate for the catalytic decomposition of hydrogen peroxide solution. This study has the best process parameters for the design and optimization of heterogeneous catalysts applied to microfluidic reactors.
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来源期刊
Catalysts
Catalysts CHEMISTRY, PHYSICAL-
CiteScore
6.80
自引率
7.70%
发文量
1330
审稿时长
3 months
期刊介绍: Catalysts (ISSN 2073-4344) is an international open access journal of catalysts and catalyzed reactions. Catalysts publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced.
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