Max Engelhardt, Hans Albert Gilg, Klaus Richter, Antoni Sanchez-Ferrer
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Control experiments with vapor-treated specimens, however, indicated that the effects were originating from the water imbibition and not due to the removal of extractives per se. This was supported by X-ray diffraction results, which were similarly affected by both vapor and extraction treatment. Therefore, the results indicate that the hygric history of the specimens was affecting the wood due to plasticization, increasing mobility, and thereby likely allowing biopolymer reconfiguration and subsequent quenching during re-drying, even though surface-free energy and wettability were not considerably affected. 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引用次数: 0
摘要
要在承重工程木制品(EWP)中使用银桦木(Betula pendula Roth),生产过程中可靠的粘接是先决条件。目前有关桦木在 EWP 应用中的粘合的知识还很有限。萃取物被认为是确保粘合质量时需要关注的一个普遍因素。因此,在本研究中,我们研究了亲水萃取物对银桦木的几种与粘合相关的体积和表面特性的影响,例如吸湿性、膨胀行为、微观结构、润湿性和机械特性。萃取过程略微影响了水汽吸附,导致膨胀压力降低。从压缩试验中可以看出,萃取还导致杨氏模量降低。然而,用蒸汽处理过的试样进行的对照实验表明,这些影响是由水浸泡造成的,而不是由于萃取物本身的去除。这一点也得到了 X 射线衍射结果的支持,蒸发和萃取处理对 X 射线衍射结果的影响相似。因此,尽管表面自由能和润湿性没有受到很大影响,但结果表明,试样的吸湿历史对木材产生了影响,原因是塑化、流动性增加,从而可能使生物聚合物重新配置,并在再干燥过程中淬火。这些变化在多大程度上是永久性的还是暂时性的,仍是一个有待研究的问题。
Adhesion-related properties of silver birch (Betula Pendula Roth) wood as affected by hydrophilic extraction
For the utilization of silver birch (Betula pendula Roth) in load-bearing engineered wood products (EWPs), reliable bonding in production is a prerequisite. The current knowledge regarding the bonding of birch in EWP applications is limited. Extractives are considered a general factor of attention when securing bonding quality. Thus, in this study, the effects of hydrophilic extractives on several adhesion-related bulk and surface properties of silver birch wood were studied, e.g., vapor sorption, swelling behavior, microstructure, wettability, and mechanical properties. The extraction procedure slightly affected vapor sorption causing a reduction in swelling pressure. The extraction also led to a lower Young's modulus, as seen by compression tests. Control experiments with vapor-treated specimens, however, indicated that the effects were originating from the water imbibition and not due to the removal of extractives per se. This was supported by X-ray diffraction results, which were similarly affected by both vapor and extraction treatment. Therefore, the results indicate that the hygric history of the specimens was affecting the wood due to plasticization, increasing mobility, and thereby likely allowing biopolymer reconfiguration and subsequent quenching during re-drying, even though surface-free energy and wettability were not considerably affected. The extent to which these changes appear permanently or temporarily remains an open research question.
期刊介绍:
Wood Science and Technology publishes original scientific research results and review papers covering the entire field of wood material science, wood components and wood based products. Subjects are wood biology and wood quality, wood physics and physical technologies, wood chemistry and chemical technologies. Latest advances in areas such as cell wall and wood formation; structural and chemical composition of wood and wood composites and their property relations; physical, mechanical and chemical characterization and relevant methodological developments, and microbiological degradation of wood and wood based products are reported. Topics related to wood technology include machining, gluing, and finishing, composite technology, wood modification, wood mechanics, creep and rheology, and the conversion of wood into pulp and biorefinery products.