在高压层压板生产中添加硼砂作为缓冲剂对三聚氰胺-甲醛树脂储存稳定性的影响

Abdul Halim Muslem, Rahmi Rahmi, Midia Fujiani
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摘要

高压层压板(HPL)是热固性树脂在人造板方面的应用之一,可用作建筑家具的保护板和装饰板。三聚氰胺-甲醛(MF)树脂是在高压层压板生产中发挥作用的树脂之一。由于在储存过程中游离的三聚氰胺甲醇之间会发生交联,并伴随着 pH 值的降低,这种树脂的储存稳定性较低。本研究旨在通过添加硼砂作为缓冲剂来提高三聚氰胺甲醛树脂的储存稳定性。三聚氰胺甲醛树脂的合成是通过聚合和缩合步骤进行的,然后在达到终点时加入浓度为 0、0.5、1、1.5 和 2% 的硼砂。树脂的表征包括树脂的物理和化学参数分析,以及通过傅立叶变换红外光谱分析树脂的官能团。通过每日目视观察以及测定 pH 值和粘度的每日变化,对 MF 树脂的储存稳定性进行了研究。MF 树脂还被进一步用于生产高压层压板。高压层压板的表征包括基于 SNIISO4586-7:2017 的质量分析和光泽度分析。在这项研究中,1.5% MF 硼砂树脂具有最高的储存稳定性,即 11 天。高压层压板质量分析符合 SNIISO4586-7:2017 标准。使用 1.5% 中链硼砂树脂的高压层压板光泽度最高,达到 115。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Effect of Borax Addition as Buffering Agent on Storage Stability of Melamine-Formaldehyde Resin in the Production of High-Pressure Laminates
High-pressure laminates (HPL) is one of the applications of thermosetting resins for wood-based materials as protective and decorative panels covering building furniture. Melamine-formaldehyde (MF) resin is one of the resins that play a role in the production of high-pressure laminates. This resin has low storage stability due to cross-linking between free melamine methylols accompanied by a decrease in pH during the storage process. This study aims to improve the storage stability of melamine-formaldehyde resin by adding borax as a buffering agent. Synthesis of MF resin was conducted by polymerization and condensation steps followed by the addition of borax at concentrations of 0, 0.5, 1, 1.5, and 2% when the endpoint was reached. The characterization of the resin includes the analysis of the physical and chemical parameters of the resin and the analysis of the functional groups of the resin by FT-IR. Storage stability study of MF resin was carried out by daily visual observation and determination of daily changes in pH and viscosity. MF resin was further used in the production of high-pressure laminates. High-pressure laminates characterization includes quality analysis based on SNIISO4586-7:2017 and analysis gloss level. In this study, 1.5% MF borax resin had the highest storage stability, namely 11 days. HPL quality analysis complies with SNIISO4586-7:2017 standards. High-pressure laminates of 1.5% borax MF resin has the highest gloss level, which is 115.
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