分析在用含钒钛磁铁矿冶炼铸铁的条件下用氢代替碳的可能性

S. I. Minin, D. A. Koshkarov, A. A. Forshev, K. V. Mironov, L. Gileva, M. Polovets, S. Zagainov
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引用次数: 0

摘要

黑色冶金企业二氧化碳排放总量的 75% 是在高炉过程中产生的。生铁生产中二氧化碳减排的方向之一是用氢气作为还原剂部分替代一氧化碳。研究表明,这种替代可减少直接还原氧化铁的热量消耗,从而降低总碳消耗量。利用高炉工艺数学模型,对氢添加剂部分替代工艺燃料(焦炭、天然气、煤粉)的效率进行了评估。计算是在 EVRAZ NTMK JSC 公司熔化含钒钛磁铁矿的高炉运行条件下进行的。计算了用氢替代工艺燃料的系数和用氢替代工艺燃料对二氧化碳排放量变化的影响系数。确定了在鼓风流量恒定的情况下,窑炉生产率的变化与氢气消耗量的关系,以及为保持压降而对氢气消耗量进行的调整。结果表明,在没有煤气动力储备的情况下,用氢气替代工艺燃料会导致熔炉生产率下降。用氢气替代工艺燃料熔炼钛磁铁矿生铁时,由于钛碳化物和碳氮化物的形成增加,熔炼产品的精炼将变得复杂。与纯氢替代 0.73 kg/m3 相比,氢气进入高炉时与天然气形成的二氧化碳减少了 0.35 kg/m3,这还不包括制氢过程中的二氧化碳排放。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Analysis of the possibility of replacing carbon with hydrogen in the conditions of smelting cast iron from vanadium-containing titanomagnetites
75 % of the total carbon dioxide emissions by ferrous metallurgy enterprises is generated in the blast furnace process. One of the directions of CO2 emission reduction in pig iron production is partial replacement of carbon monoxide with hydrogen as a reducing agent. It is shown that such a replacement can lead to a decrease in the total carbon consumption due to reduction of heat consumption for the direct reduction of iron oxides. Using a mathematical model of the blast furnace process, the efficiency of partial replacement of process fuel (coke, natural gas, pulverized coal) with a hydrogen additive was evaluated. Calculations were performed for the operating conditions of blast furnaces of EVRAZ NTMK JSC, which melt vanadium-containing titanomagnetites. The coefficients of process fuel replacement with hydrogen and the coefficients of the influence of the replacement of process fuel with hydrogen on the change in CO2 emissions are calculated. The dependence of the change in the productivity of the furnace on the consumption of hydrogen at a constant minute flow rate of the blast and its adjustment to maintain the pressure drop has been established. It is shown that in the absence of gas dynamics reserves, the replacement of process fuel with hydrogen will be accompanied by a decrease in furnace productivity. The smelting of pig iron from titanomagnetites with the replacement of technological fuel with hydrogen will complicate the refining of melting products due to an increase in the formation of titanium carbides and carbonitrides. The reduction in CO2 formation at hydrogen entering the blast furnace with natural gas is 0.35 kg/m3 compared to pure hydrogen replacement of 0.73 kg/m3, not taking into account CO2 emission during hydrogen production
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