Sagarkumar Rajendrakumar Shah, N. J. Mazumdar, Ander Centeno-Pedrazo, D. Deka, N. Artioli, H. Manyar
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引用次数: 0
摘要
二氧化碳作为一种可再生和可持续的 C1 原料,是羧化反应的理想原料,并因其低成本、无毒性和高丰度而得到广泛认可。为了降低导致温室气体效应的二氧化碳在环境中的浓度,开发新的利用二氧化碳进行有机合成的催化方案具有重要意义。本综述侧重于以二氧化碳为 C1 原料的羧化反应,通过催化生成的烯丙基金属中间体、光氧化催化和电催化合成高附加值的功能化羧酸及其相应衍生物,重点介绍羧化反应催化剂设计方面的最新进展和机遇。在本文中,我们将介绍在不同条件下以 CO2 为 C1 源进行各种反应的 C-H 键、烯烃和炔烃羧化反应的最新进展,以及在有机合成中进一步开发 CO2 利用的潜在方向。
Recent Advances in Catalyst Design for Carboxylation Using CO2 as the C1 Feedstock
Carbon dioxide is ideal for carboxylation reactions as a renewable and sustainable C1 feedstock and has significant recognition owing to its low cost, non-toxicity, and high abundance. To depreciate the environmental concentration of CO2, which causes the greenhouse gas effect, developing new catalytic protocols for organic synthesis in CO2 utilization is of great importance. This review focuses on carboxylation reactions using CO2 as a C1 feedstock to synthesize value-added functionalized carboxylic acids and their corresponding derivatives via catalytically generated allyl metal intermediates, photoredox catalysis, and electrocatalysis with a focus on recent developments and opportunities in catalyst design for carboxylation reactions. In this article, we describe recent developments in the carboxylation of C–H bonds, alkenes, and alkynes using CO2 as the C1 source for various reactions under different conditions, as well as the potential direction for the further development of CO2 utilization in organic synthesis.
期刊介绍:
Catalysts (ISSN 2073-4344) is an international open access journal of catalysts and catalyzed reactions. Catalysts publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced.