锅炉灰去除 Reafix Yellow B8G 染料的动力学研究

IgMin Research Pub Date : 2023-12-13 DOI:10.61927/igmin127
Prinz Peterson Filisbino, Hawerroth Mariane, de Lima Liliane Schier, de Abreu Pietrobelli Juliana Martins Teixeira
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引用次数: 0

摘要

纺织业在巴西的社会经济中占有重要地位,它产生了大量成分各异的废水,其中染料是最令人担忧的污染物之一,因为它们具有高溶解性、有害性和低降解性等特点。其中,Reafix 黄 B8G(ARB8G)染料具有偶氮性质,对水生环境中的生物有害。根据巴西法律,由于其抗生物降解性,建议通过焚烧或填埋的方式处理废物。处理污水的方法之一是使用具有吸附能力的材料吸附污染物,例如锅炉燃烧生物质的残渣(灰烬)。这项工作的总体目标是通过锅炉灰的接触时间来评估 ARB8G 染料的吸附动力学。测试方法是将吸附剂材料与 75 mg.L-1 的染料溶液混合,在恒温和不同时间间隔内搅拌。为了量化吸附的染料量,采用了紫外可见光谱法。动力学测试表明,在测试条件下,平衡时间为 30 分钟,去除率为 100%。根据这一结果,并考虑到锅炉残渣是一种利用率低、成本低的材料,可以得出结论,这种物质作为一种替代材料,在处理含有染料的废水方面具有很大的应用潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Kinetic Study of the Removal of Reafix Yellow B8G Dye by Boiler Ash
The textile sector has great relevance in the Brazilian socioeconomic context, generating large volumes of effluents of varied composition, with dyes being one of the most worrying contaminants due to their characteristics of high solubility, harmfulness and low degradability. Among them the Reafix Yellow B8G (ARB8G) dye has an azo nature, harmful to organisms in the aquatic environment. According to Brazilian laws, it is recommended to dispose of waste through incineration or landfill, due to its resistance to biodegradation. One of the methods for treating effluents is the adsorption of contaminants using materials with adsorption capacity, such as residue from the burning of biomass in boilers (ash). The general objective of this work was to evaluate the adsorption kinetics by contact time of the ARB8G dye by boiler ash. The test was based on mixing the adsorbent material with a dye solution at 75 mg.L-1, at constant temperature and stirring at different time intervals. To quantify the amount of adsorbed dye, the UV-Vis spectrometry method was used. The kinetic test indicated an equilibrium time of 30 minutes, with 100% removal under the tested conditions. From this result and considering that boiler residue is an underutilized and low-cost material, it is concluded that this substance has significant potential to be applied as an alternative material for the treatment of effluents containing dyes.
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