洞察嘌呤提库斯在缓慢热解过程中的降解行为和动力学原理

O. Farobie, A. Amrullah
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引用次数: 0

摘要

Purun tikus(Elocharis dulcis)是一种湿地生物质原料,是对沼泽生态系统的挑战,因为它会造成该地区的污染。因此,整合使用 purun tikus 作为生物能源,特别是生物油形式的生物能源,是当务之急。然而,目前还缺乏对通过热解将 purun tikus 转化为生物油的降解率的研究。因此,本研究旨在评估 purun tikus 通过热解转化为生物油过程中的破坏率。实验采用间歇式反应容器,在 300 至 500 °C 温度范围内进行缓慢热解,反应时间为 60 至 120 分钟。通过假设一阶过程和使用阿伦尼乌斯方程,可以计算出活化能和前指数。为了确定 purun tikus 是否在热解过程中破坏,确定了 43.317 kJ mol-1 的活化能和 0.351 s-1 的预指数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Insights into the behavior and kinetics of purun tikus degradation during slow pyrolysis
Purun tikus (Elocharis dulcis), a type of wetland biomass feedstock, is a challenge to the swamp ecosystem as it contributes to pollution in the area. Hence, integrating the use of purun tikus as a source of bioenergy, particularly in the form of bio-oil, is of the highest priority. Nevertheless, there is a lack of research on the degradation rate of purun tikus conversion to bio-oil through pyrolysis. Thus, this study aims to evaluate the rate of destruction of purun tikus in the process of conversion into bio-oil via pyrolysis. In the experiment, a batch reaction vessel was used to carry out slow pyrolysis at temperatures ranging from 300 to 500 °C, and the reaction times ranged from 60 to 120 min. By assuming a first-order process and using the Arrhenius equation, it was possible to figure out the activation energy and the preexponential factort. To determine whether purun tikus destroyed during pyrolysis, an activation energy of 43.317 kJ mol-1 and a pre-exponential factor of 0.351 s-1 were identified.
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