用于甲酸酯和己二酸酯高性能耦合电合成的自支撑双金属阵列上层结构

Li Liu, Yingchun He, Qing Li, Changsheng Cao, Minghong Huang, Dong-Dong Ma, Xin-Tao Wu, Qi-Long Zhu
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引用次数: 0

摘要

涉及二氧化碳升级转化的耦合电合成对环境和能源的可持续发展具有重要意义,但具有一定的挑战性。在此,我们以 Cu(OH)2 阵列结构为前驱体,精心构建了自支撑双金属阵列超结构,可在阳极和阴极分别实现甲酸酯和己二酸酯的高性能耦合电合成。具体地说,在两个电极上,二氧化碳转化为甲酸盐和环己酮转化为己二酸盐的法拉第效率(FEs)同时超过 90%,且稳定性极佳。这种高性能耦合电合成与以铜铋合金的多孔纳米片阵列上层结构为阴极、氢氧化铜镍的纳米片-纳米线阵列上层结构为阳极高度相关。此外,与传统电解过程相比,在双电极电解槽中耦合电合成的电催化性能保持不变的情况下,电池电压大幅降低,FEformate 和 FEadipate 的最大值分别达到 94.2% 和 93.1%。实验结果进一步证明,双金属成分调节了局部电子结构,促进了向目标产物的反应。展望未来,我们的工作为构建自适应自支撑超结构以实现高效耦合电合成提出了一种具有指导意义的策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Self-supported bimetallic array superstructures for high-performance coupling electrosynthesis of formate and adipate

Self-supported bimetallic array superstructures for high-performance coupling electrosynthesis of formate and adipate

The coupling electrosynthesis involving CO2 upgrade conversion is of great significance for the sustainable development of the environment and energy but is challenging. Herein, we exquisitely constructed the self-supported bimetallic array superstructures from the Cu(OH)2 array architecture precursor, which can enable high-performance coupling electrosynthesis of formate and adipate at the anode and the cathode, respectively. Concretely, the faradaic efficiencies (FEs) of CO2-to-formate and cyclohexanone-to-adipate conversion simultaneously exceed 90% at both electrodes with excellent stabilities. Such high-performance coupling electrosynthesis is highly correlated with the porous nanosheet array superstructure of CuBi alloy as the cathode and the nanosheet-on-nanowire array superstructure of CuNi hydroxide as the anode. Moreover, compared to the conventional electrolysis process, the cell voltage is substantially reduced while maintaining the electrocatalytic performance for coupling electrosynthesis in the two-electrode electrolyzer with the maximal FEformate and FEadipate up to 94.2% and 93.1%, respectively. The experimental results further demonstrate that the bimetal composition modulates the local electronic structures, promoting the reactions toward the target products. Prospectively, our work proposes an instructive strategy for constructing adaptive self-supported superstructures to achieve efficient coupling electrosynthesis.

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