K. M. Salikhov, A. A. Sukhanov, I. T. Khairutdinov
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引用次数: 0
摘要
对处于单子自旋态的模型自由基对(RPs)的主电子自旋回波信号的相位进行了分析。对文献中已知的事实进行了解释,即这种自由基对的回波信号可能没有 "正常 "相位的分量,而 "正常 "相位是对自由基对中非相互作用的未成对电子的回波信号的预期。研究首次从理论上证明,禁用的 EPR 转变会对 RP 自旋磁化的相移做出重要贡献,而这是由 RP 非配对电子与磁核的偶极-偶极超频相互作用引起的。自由基对中相互作用的自旋回波信号的 "反常 "相位表明,自旋动力学伴随着偶极子极化(自旋磁化)和四极子自旋极化的可逆转变。
Features of the Primary Electron Spin Echo Signal for Spin-Correlated Radical Pairs
The phase of the primary electron spin echo signal was analyzed on model radical pairs (RPs) in a singlet spin state. An interpretation is given of the fact known in the literature that the echo signal of such pairs may not have a component with a “normal” phase, which is expected for the echo signal of non-interacting unpaired electrons in the RP. For the first time, it has been theoretically shown that forbidden EPR transitions can make a significant contribution to the phase shift of the magnetization of RP spins, caused by the dipole–dipole hyperfine interaction of unpaired RP electrons with magnetic nuclei. The “anomalous” phase of the spin echo signal of interacting spins in radical pairs is a demonstration that spin dynamics is accompanied by reversible transitions of dipole polarization (spin magnetization) and quadrupole spin polarization.
期刊介绍:
Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields.
The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.