{"title":"通过先进的 MOCVD 技术,在 4.2 K 和 13 T 条件下,40 米长的 REBCO 带临界电流超过 4,000 A/12 mm","authors":"Mahesh Paidpilli , Chirag Goel , Bhabesh Sarangi , Siwei Chen , Eduard Galstyan , Jan Jaroszynski , Griffin Bradford , Dmytro Abraimov , Venkat Selvamanickam","doi":"10.1016/j.supcon.2023.100081","DOIUrl":null,"url":null,"abstract":"<div><p>REBa<sub>2</sub>Cu<sub>3</sub>O<sub>7−δ</sub> (REBCO, RE = rare earth) tapes doped with 5% and 15% Zr have been scaled up to lengths more than 40 m in a pilot-scale advanced metal organic chemical vapor deposition (A-MOCVD) tool<em>.</em> The precursor compositions used for the long tapes were guided by a study of the influence of (Ba + dopant)/Cu content on the critical current density (<em>J<sub>c</sub></em>) of 5 and 15 mol.% Hf- and Zr-added tapes at 4.2 K and 13 T. The 40-m-long tapes exhibited a critical current (<em>I<sub>c</sub></em>) over 4,000 A/12 mm at 4.2 K and 13 T as well as over 1,400 A/12 mm at 20 K and 20 T. The critical current densities of a 40-m-long tape doped with 5% Zr at 4.2 K measured at the National High Magnetic Field Laboratory (NHMFL) were > 10 MAcm<sup>−2</sup> and >5 MAcm<sup>−2</sup> at 14 T and 30 T, respectively, which are over three times those of commercial REBCO tapes. The infield <em>J<sub>c</sub></em> of 5% Zr-added 40-m-long tapes was similar to those of previously-reported high-performance short samples made with 15% Zr or Hf. These results demonstrate the excellent potential of A-MOCVD for manufacturing high <em>I<sub>c</sub></em> REBCO tapes for use in ultrahigh-field magnet applications.</p></div>","PeriodicalId":101185,"journal":{"name":"Superconductivity","volume":"9 ","pages":"Article 100081"},"PeriodicalIF":5.6000,"publicationDate":"2023-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772830723000467/pdfft?md5=68567b29316d49e6d356ab3cbd87f05b&pid=1-s2.0-S2772830723000467-main.pdf","citationCount":"0","resultStr":"{\"title\":\"40-meter-long REBCO tapes with critical current over 4,000 A/12 mm at 4.2 K and 13 T by advanced MOCVD\",\"authors\":\"Mahesh Paidpilli , Chirag Goel , Bhabesh Sarangi , Siwei Chen , Eduard Galstyan , Jan Jaroszynski , Griffin Bradford , Dmytro Abraimov , Venkat Selvamanickam\",\"doi\":\"10.1016/j.supcon.2023.100081\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>REBa<sub>2</sub>Cu<sub>3</sub>O<sub>7−δ</sub> (REBCO, RE = rare earth) tapes doped with 5% and 15% Zr have been scaled up to lengths more than 40 m in a pilot-scale advanced metal organic chemical vapor deposition (A-MOCVD) tool<em>.</em> The precursor compositions used for the long tapes were guided by a study of the influence of (Ba + dopant)/Cu content on the critical current density (<em>J<sub>c</sub></em>) of 5 and 15 mol.% Hf- and Zr-added tapes at 4.2 K and 13 T. The 40-m-long tapes exhibited a critical current (<em>I<sub>c</sub></em>) over 4,000 A/12 mm at 4.2 K and 13 T as well as over 1,400 A/12 mm at 20 K and 20 T. The critical current densities of a 40-m-long tape doped with 5% Zr at 4.2 K measured at the National High Magnetic Field Laboratory (NHMFL) were > 10 MAcm<sup>−2</sup> and >5 MAcm<sup>−2</sup> at 14 T and 30 T, respectively, which are over three times those of commercial REBCO tapes. The infield <em>J<sub>c</sub></em> of 5% Zr-added 40-m-long tapes was similar to those of previously-reported high-performance short samples made with 15% Zr or Hf. These results demonstrate the excellent potential of A-MOCVD for manufacturing high <em>I<sub>c</sub></em> REBCO tapes for use in ultrahigh-field magnet applications.</p></div>\",\"PeriodicalId\":101185,\"journal\":{\"name\":\"Superconductivity\",\"volume\":\"9 \",\"pages\":\"Article 100081\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2023-12-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2772830723000467/pdfft?md5=68567b29316d49e6d356ab3cbd87f05b&pid=1-s2.0-S2772830723000467-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Superconductivity\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2772830723000467\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Superconductivity","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772830723000467","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
摘要
在中试规模的先进金属有机化学气相沉积(A-MOCVD)工具中,掺杂 5% 和 15% Zr 的 REBa2Cu3O7-δ(REBCO,RE = 稀土)带的长度已超过 40 米。在 4.2 K 和 13 T 条件下,(Ba + 掺杂剂)/Cu 含量对 5 和 15 mol.% Hf- 和 Zr- 添加带的临界电流密度 (Jc) 的影响研究指导了长带所用的前驱体成分。在国家高磁场实验室(NHMFL)测量到的 4.2 K 时掺杂 5% Zr 的 40 m 长磁带在 14 T 和 30 T 时的临界电流密度分别为 10 MAcm-2 和 5 MAcm-2,是商用 REBCO 磁带的三倍多。添加 5% Zr 的 40 m 长胶带的内场 Jc 与之前报道的使用 15% Zr 或 Hf 制成的高性能短样品的内场 Jc 相似。这些结果证明了 A-MOCVD 在制造超高磁场应用中使用的高 Ic REBCO 磁带方面的巨大潜力。
40-meter-long REBCO tapes with critical current over 4,000 A/12 mm at 4.2 K and 13 T by advanced MOCVD
REBa2Cu3O7−δ (REBCO, RE = rare earth) tapes doped with 5% and 15% Zr have been scaled up to lengths more than 40 m in a pilot-scale advanced metal organic chemical vapor deposition (A-MOCVD) tool. The precursor compositions used for the long tapes were guided by a study of the influence of (Ba + dopant)/Cu content on the critical current density (Jc) of 5 and 15 mol.% Hf- and Zr-added tapes at 4.2 K and 13 T. The 40-m-long tapes exhibited a critical current (Ic) over 4,000 A/12 mm at 4.2 K and 13 T as well as over 1,400 A/12 mm at 20 K and 20 T. The critical current densities of a 40-m-long tape doped with 5% Zr at 4.2 K measured at the National High Magnetic Field Laboratory (NHMFL) were > 10 MAcm−2 and >5 MAcm−2 at 14 T and 30 T, respectively, which are over three times those of commercial REBCO tapes. The infield Jc of 5% Zr-added 40-m-long tapes was similar to those of previously-reported high-performance short samples made with 15% Zr or Hf. These results demonstrate the excellent potential of A-MOCVD for manufacturing high Ic REBCO tapes for use in ultrahigh-field magnet applications.