确定乌克兰西部地区乳品加工厂废水的形成规律和化学成分

Leonid Bytsyura, Yurii Senyk, Iryna Barna
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Polluted wastewater is produced after cleaning equipment, industrial pipelines, automobile tanks, floors, industrial premise panels, etc. Partly polluted wastewater is produced as a result of the cooling processes of milk and equipment. Both types of wastewater form a common flow that is subject to cleaning, disinfection and discharge into drainage systems or surface water bodies (depending on the chemical composition). \nThe study of the wastewater composition of a dairy processing plant was divided into two stages. At the first stage, the analysis of mixed phases formed during the production process in each section of the factory was carried out. \nThe analysis was carried out for one day of production at a dairy factory that processed 496 tons of whole milk, of which 170 tons were used to make whole milk products and cottage cheese, and the rest were used to make butter and casein. At the same time, 1200 m3 of water was used for all production processes, and additional water consumption for auxiliary processes and services amounted to 643 m3, so the total discharge per day was 2000.47 m3. \nThe next step was to directly analyse the wastewater indicators of the dairy processing plant. To offset the impact of the production process on the composition of dairy wastewater and the volume of manufactured products, we organized sampling every two hours for four days. As a result, 48 points of analysis were obtained, which allowed us to form an objective assessment of the factory’s discharge. \nAs a result of the research, the regularities and sources of formation of wastewater were established, and the chemical composition of wastewater from a dairy processing plant in the Western region of Ukraine was experimentally determined. The results obtained allowed us to draw the following conclusions. 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引用次数: 0

摘要

乳制品行业的终端加工产品种类繁多,按惯例可分为液态、固态和干态产品。第一类包括巴氏杀菌奶、奶油和发酵乳饮料(酸乳酒、酸奶、甜点),第二类包括黄油和奶酪,第三类包括干奶(全脂或脱脂)、各种成分和纯度的蛋白质、酪蛋白和乳清。乳制品厂的废水是各种技术和生产过程的结果,这些过程在时间上各不相同,因此其产品不会同时排放,这就决定了会形成不同成分和体积的废水。乳品厂产生的工业废水分为两类:污染废水和部分污染废水。污染废水是在清洗设备、工业管道、汽车油箱、地板、工业前提板等之后产生的。部分污染废水是在牛奶和设备冷却过程中产生的。这两种废水形成一个共同的流体,经过清洗、消毒后排入排水系统或地表水体(取决于化学成分)。对乳品加工厂废水成分的研究分为两个阶段。在第一阶段,对工厂各部门在生产过程中形成的混合相进行了分析。分析是在一家加工 496 吨全脂牛奶的乳品厂一天的生产过程中进行的,其中 170 吨用于制作全脂牛奶产品和松软干酪,其余用于制作黄油和酪蛋白。同时,所有生产工序用水量为 1200 立方米,辅助工序和服务的额外用水量为 643 立方米,因此每天的总排水量为 2000.47 立方米。下一步是直接分析乳品加工厂的废水指标。为了抵消生产过程对乳品废水成分和制成品量的影响,我们在四天内每两小时组织一次采样。因此,我们获得了 48 个分析点,从而对工厂的排放情况形成了客观的评估。研究结果确定了废水形成的规律和来源,并通过实验确定了乌克兰西部地区一家乳品加工厂废水的化学成分。根据研究结果,我们得出了以下结论。总径流的形成是由技术过程和相关过程造成的,其中包括突然排放主要污染物浓度较高的高污染废水、在技术过程中使用不同量的水、白天废水的量和成分不同。因此,要正确评估奶制品工厂排放物的成分,需要进行系统和长期的研究,而不是定点分析。根据乌克兰有关向污水系统和城市生物处理设施排放废水的法律规定的主要指标,对废水的化学成分进行了实验研究。获得的数据表明,乳品加工厂总废水的化学成分不符合要求。主要污染物有:有机成分,平均超过化学需氧量的三倍,高峰时超过 10 倍;磷酸盐(总磷)超过 8-22 倍,氯化物超过 2-7 倍。对各个技术阶段的比较表明,污染最严重的废水是在酸性酪蛋白生产过程中产生的。这些废水的特点是化学需氧量、氯化物和磷酸盐的数值较高,它们对这些指标的总体数值起着决定性作用。全脂奶产品生产过程中 COD 略有超标。因此,为了防止城市生物处理设施中活性污泥的死亡,有必要对废水进行预处理,以使上述指标符合标准。关键词:乳品业、乳品加工厂、废水、废水化学成分、乌克兰西部地区。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ESTABLISHMENT OF THE LAWS OF FORMATION AND CHEMICAL COMPOSITION OF WASTEWATER OF A DAIRY PROCESSING PLANT IN THE WESTERN REGION OF UKRAINE
The dairy industry has a wide range of processing end products, which can be conventionally divided into liquid, solid and dry products. The first group includes pasteurized milk, cream and fermented milk drinks (kefir, yoghurt, desserts), the second group includes butter and cheese, the third group includes dry milk (whole or skim), proteins of various composition and purity, casein and whey. The wastewater of a dairy factory is the result of various technological and production processes, which vary in time and, accordingly, their products are not discharged simultaneously, which determines the formation of effluents of different compositions and volumes. Industrial wastewater generated at dairy factories is divided into two types: polluted and partly polluted wastewater. Polluted wastewater is produced after cleaning equipment, industrial pipelines, automobile tanks, floors, industrial premise panels, etc. Partly polluted wastewater is produced as a result of the cooling processes of milk and equipment. Both types of wastewater form a common flow that is subject to cleaning, disinfection and discharge into drainage systems or surface water bodies (depending on the chemical composition). The study of the wastewater composition of a dairy processing plant was divided into two stages. At the first stage, the analysis of mixed phases formed during the production process in each section of the factory was carried out. The analysis was carried out for one day of production at a dairy factory that processed 496 tons of whole milk, of which 170 tons were used to make whole milk products and cottage cheese, and the rest were used to make butter and casein. At the same time, 1200 m3 of water was used for all production processes, and additional water consumption for auxiliary processes and services amounted to 643 m3, so the total discharge per day was 2000.47 m3. The next step was to directly analyse the wastewater indicators of the dairy processing plant. To offset the impact of the production process on the composition of dairy wastewater and the volume of manufactured products, we organized sampling every two hours for four days. As a result, 48 points of analysis were obtained, which allowed us to form an objective assessment of the factory’s discharge. As a result of the research, the regularities and sources of formation of wastewater were established, and the chemical composition of wastewater from a dairy processing plant in the Western region of Ukraine was experimentally determined. The results obtained allowed us to draw the following conclusions. The formation of the total runoff is caused by both technological and related processes, which include sudden emissions of highly polluted wastewater with a high concentration of major pollutants, the use of different volumes of water for technological processes, and different volumes and composition of wastewater during the day. Therefore, to correctly assess the composition of a dairy factory's discharge, a systematic and long-term study is required, rather than a spot analysis. The chemical composition of wastewater was experimentally studied according to the main indicators regulated by the legislation of Ukraine regarding the discharge of wastewater into the sewage system and municipal biological treatment facilities. The data obtained indicates that the chemical composition of the total wastewater from the dairy processing plant does not meet the requirements. The main pollutants are: organic components, which are expressed in exceeding the chemical oxygen demand on average by three times, and at the peak load - by 10 times; phosphates in terms of total phosphorus - by 8-22 times and chlorides - by 2-7 times. A comparative characterization of individual technological stages shows that the most polluted wastewater is generated in the process of acid casein production. These waters are characterized by high values of COD, chlorides and phosphates, and their contribution to the overall value of these indicators is determinant. The production of whole milk products is characterized by a slight excess of COD. As a result, in order to prevent the death of activated sludge in municipal biological treatment facilities, pretreatment of wastewater is necessary to bring the above indicators to the norms. Key words: dairy industry, dairy processing plant, wastewater, wastewater chemical composition, the Western region of Ukraine.
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