1-Adamantylaminogermylene 的合成及其钙化反应

IF 2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2023-12-21 DOI:10.1002/ejic.202300663

Dr. Mariko Yukimoto, Kazuaki Kanda, Takamasa Aoki, Dr. Yoshiyuki Mizuhata, Prof. Norihiro Tokitoh

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引用次数: 0

摘要

利用锗原子上的大芳基的动力学稳定作用，实现了 1-金刚烷基氨基锗 1 的合成、分离和表征。研究发现，氨基锗 1 在 110 °C 的甲苯溶液中可稳定存在 3 天而不分解。以合成重酰胺为目的的 1 的羰基化反应产生了相应重酰胺的头尾型二聚物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis of 1-Adamantylaminogermylene and Its Chalcogenation Reactions

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Synthesis of 1-Adamantylaminogermylene and Its Chalcogenation Reactions

The synthesis, isolation, and characterization of 1-adamantylaminogermylene 1 have been achieved utilizing kinetic stabilization with a bulky aryl group on the germanium atom. Aminogermylene 1 was found to be stable in toluene solution at 110 °C for 3 days without decomposition. The chalcogenation reaction of 1 aiming to synthesize heavy amides gave the head-to-tail type dimers of the corresponding heavy amides.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.