J. Tepsell, Y. Lahaye, F. Molnár, O.T. Rämö, N. Cook
{"title":"芬兰拉普兰拉贾帕洛特共富集金矿床原生金的银同位素分析和系统学研究","authors":"J. Tepsell, Y. Lahaye, F. Molnár, O.T. Rämö, N. Cook","doi":"10.1007/s00126-023-01239-y","DOIUrl":null,"url":null,"abstract":"<p>Silver is probably the closest isotopic proxy to track monoisotopic gold and has been shown to have great potential to yield new information on the origin and enrichment processes of gold. This study describes the development of a tailored analytical protocol for accurate analysis of Ag isotopes and provides the first Ag isotope data for the Paleoproterozoic Rajapalot Au-Co deposit, Finnish Lapland. Six native Au samples yield ε<sup>109</sup>Ag values (relative to NIST SRM 978a) from −6.8 to +2.1 and are within the range of Ag isotopic compositions reported for native Au samples. The mean of the analyzed Au samples is ε<sup>109</sup>Ag = −3.8 ± 1.7 (2SD) with most of the samples with negative ε<sup>109</sup>Ag values (−6.7 to −2.0); one sample has a positive ε<sup>109</sup>Ag value of +2.1 ± 0.5. Silver isotope fractionation in the Rajapalot Au deposit was likely associated with physicochemical processes related to deposition and/or re-mobilization of the ore rather than with source region inheritance. It is suggested that redox reactions involving Ag<sup>+</sup> ↔ Ag<sup>0</sup> phase change primarily account for the isotopic differences within the deposit. Our results also suggest that the Rajapalot Au-Co deposit was formed via multistage ore-forming processes and/or that the primary ore was re-mobilized, which caused isotope fractionation along fluid pathways. Silver isotope variation within a deposit may mark a fractional crystallization trend with the lightest isotopic composition representing the earliest precipitate. Hence, Ag isotopes show potential as an isotopic vectoring tool in search of Au-enriched domains.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.4000,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Silver isotope analysis and systematics of native gold from the Rajapalot Co-enriched gold deposit, Finnish Lapland\",\"authors\":\"J. Tepsell, Y. Lahaye, F. Molnár, O.T. Rämö, N. Cook\",\"doi\":\"10.1007/s00126-023-01239-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Silver is probably the closest isotopic proxy to track monoisotopic gold and has been shown to have great potential to yield new information on the origin and enrichment processes of gold. This study describes the development of a tailored analytical protocol for accurate analysis of Ag isotopes and provides the first Ag isotope data for the Paleoproterozoic Rajapalot Au-Co deposit, Finnish Lapland. Six native Au samples yield ε<sup>109</sup>Ag values (relative to NIST SRM 978a) from −6.8 to +2.1 and are within the range of Ag isotopic compositions reported for native Au samples. The mean of the analyzed Au samples is ε<sup>109</sup>Ag = −3.8 ± 1.7 (2SD) with most of the samples with negative ε<sup>109</sup>Ag values (−6.7 to −2.0); one sample has a positive ε<sup>109</sup>Ag value of +2.1 ± 0.5. Silver isotope fractionation in the Rajapalot Au deposit was likely associated with physicochemical processes related to deposition and/or re-mobilization of the ore rather than with source region inheritance. It is suggested that redox reactions involving Ag<sup>+</sup> ↔ Ag<sup>0</sup> phase change primarily account for the isotopic differences within the deposit. Our results also suggest that the Rajapalot Au-Co deposit was formed via multistage ore-forming processes and/or that the primary ore was re-mobilized, which caused isotope fractionation along fluid pathways. Silver isotope variation within a deposit may mark a fractional crystallization trend with the lightest isotopic composition representing the earliest precipitate. 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Silver isotope analysis and systematics of native gold from the Rajapalot Co-enriched gold deposit, Finnish Lapland
Silver is probably the closest isotopic proxy to track monoisotopic gold and has been shown to have great potential to yield new information on the origin and enrichment processes of gold. This study describes the development of a tailored analytical protocol for accurate analysis of Ag isotopes and provides the first Ag isotope data for the Paleoproterozoic Rajapalot Au-Co deposit, Finnish Lapland. Six native Au samples yield ε109Ag values (relative to NIST SRM 978a) from −6.8 to +2.1 and are within the range of Ag isotopic compositions reported for native Au samples. The mean of the analyzed Au samples is ε109Ag = −3.8 ± 1.7 (2SD) with most of the samples with negative ε109Ag values (−6.7 to −2.0); one sample has a positive ε109Ag value of +2.1 ± 0.5. Silver isotope fractionation in the Rajapalot Au deposit was likely associated with physicochemical processes related to deposition and/or re-mobilization of the ore rather than with source region inheritance. It is suggested that redox reactions involving Ag+ ↔ Ag0 phase change primarily account for the isotopic differences within the deposit. Our results also suggest that the Rajapalot Au-Co deposit was formed via multistage ore-forming processes and/or that the primary ore was re-mobilized, which caused isotope fractionation along fluid pathways. Silver isotope variation within a deposit may mark a fractional crystallization trend with the lightest isotopic composition representing the earliest precipitate. Hence, Ag isotopes show potential as an isotopic vectoring tool in search of Au-enriched domains.
期刊介绍:
The journal Mineralium Deposita introduces new observations, principles, and interpretations from the field of economic geology, including nonmetallic mineral deposits, experimental and applied geochemistry, with emphasis on mineral deposits. It offers short and comprehensive articles, review papers, brief original papers, scientific discussions and news, as well as reports on meetings of importance to mineral research. The emphasis is on high-quality content and form for all articles and on international coverage of subject matter.