自由基与碳水化合物大联盟

IF 1.5 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Helvetica Chimica Acta Pub Date : 2023-12-21 DOI:10.1002/hlca.202300218

Béatrice Quiclet-Sire, Samir Z. Zard

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引用次数: 0

摘要

摘要：这篇综述介绍了作者实验室开发的自由基反应在碳水化合物改性方面的应用。重点是巴顿-麦康比脱氧反应的无锡变体；还原脱碘反应；黄原酸盐的分子间自由基加成；黄原酸盐和碘化物的烯丙基化和乙烯基化，重点是使用烯丙基醇作为氟吡啶基醚活化的烯丙基化反应；最后是巯基糖的合成。@font-face {font-family: "MS Mincho"; panose-1:2 2 6 9 4 2 5 8 3 4; mso-font-alt: "MS 明朝"; mso-font-charset:128; mso-generic-font-family:modern; mso-font-pitch:fixed; mso-font-signature:-536870145 1791491579 134217746 0 131231 0;}@font-face {font-family："Cambria Math"; panose-1:2 4 5 3 5 4 6 3 2 4; mso-font-charset:0; mso-generic-font-family:roman; mso-font-pitch:variable; mso-font-signature:-536870145 1107305727 0 0 415 0;}@font-face {font-family："Myriad Pro"; panose-1:2 11 6 4 2 2 2 2 4; mso-font-alt:Corbel; mso-font-charset:0; mso-generic-font-family:swiss; mso-font-pitch:variable; mso-font-signature:-1610612049 1342185547 0 0 415 0;}@font-face {font-family："\@MS Mincho"; panose-1:2 2 6 9 4 2 5 8 3 4; mso-font-charset:128; mso-generic-font-family:modern; mso-font-pitch:fixed; mso-font-signature:-536870145 1791491579 134217746 0 131231 0;}p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-unhide:no; mso-style-parent:""; margin:0cm; line-height:150%; mso-pagination:widow-orphan; font-size:8.0pt; mso-bidi-font-size:12.0pt; font-family: "Myriad Pro",sans-serif; mso-fareast-font-family: "MS Mincho"; mso-bidi-font-family: "Times New Roman"; mso-ansi-language:DE; mso-fareast-language:JA;}p.div.Helv-Abstract {mso-style-name:Helv-Abstract; mso-style-unhide:no; mso-style-qformat:yes; margin-top:6.0pt; margin-right:0cm; margin-bottom:6.0pt; margin-left:0cm; text-align:justify; text-justify:inter-ideograph; line-height:150%; mso-pagination:widow-orphan; font-size:8.0pt; mso-bidi-font-size:10.0pt; font-family: "Myriad Pro",sans-serif; mso-fareast-font-family: "MS Mincho"; mso-bidi-font-family: "Times New Roman"; mso-ansi-language:EN-US; mso-fareast-language:JA;}.MsoChpDefault {mso-style-type:export-only; mso-default-props:yes; font-size:10.0pt; mso-ansi-font-size:10.0pt; mso-bidi-font-size:10.0pt; mso-fareast-font-family: "MS Mincho";}div.WordSection1 {page:WordSection1;}.

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Radicals and Carbohydrates: A Grand Alliance

This review describes applications of radical reactions developed in the authors’ laboratory for the modification of carbohydrates. It focuses on tin-free variation on the Barton-McCombie deoxygenation; on reductive de-iodination; on intermolecular radical additions of xanthates; on allylations and vinylations of xanthates and iodides, with emphasis on allylations using allylic alcohols activated as fluoropyridyl ethers; and, finally, on the synthesis of mercaptosugars.

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来源期刊

Helvetica Chimica Acta 化学-化学综合

CiteScore

3.00

自引率

0.00%

发文量

审稿时长

2.3 months

期刊介绍： Helvetica Chimica Acta, founded by the Swiss Chemical Society in 1917, is a monthly multidisciplinary journal dedicated to the dissemination of knowledge in all disciplines of chemistry (organic, inorganic, physical, technical, theoretical and analytical chemistry) as well as research at the interface with other sciences, where molecular aspects are key to the findings. Helvetica Chimica Acta is committed to the publication of original, high quality papers at the frontier of scientific research. All contributions will be peer reviewed with the highest possible standards and published within 3 months of receipt, with no restriction on the length of the papers and in full color.