2,6-双（吡唑-3-基）吡啶新镍(II)配合物中饱和转移的可能性

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2023-12-19 DOI:10.1134/S1070328423700677

D. Yu. Aleshin, I. A. Nikovskii, E. A. Khakina, A. A. Dan’shina, Yu. V. Nelyubina

{"title":"2,6-双（吡唑-3-基）吡啶新镍(II)配合物中饱和转移的可能性","authors":"D. Yu. Aleshin, I. A. Nikovskii, E. A. Khakina, A. A. Dan’shina, Yu. V. Nelyubina","doi":"10.1134/S1070328423700677","DOIUrl":null,"url":null,"abstract":"The reaction of N,N '-disubstituted 2,6-bis(pyrazol-3-yl )pyridine ligand (L) with a divalent nickel salt gave a new nickel(II) complex [Ni(L)(H2O)(THF)Cl]BPh4 (I), which was isolated in a pure state and characterized by elemental analysis, mass spectrometry, NMR spectroscopy, and X-ray diffraction (CCDC no. 2221412). According to NMR spectroscopy data combined with the results of quantum chemical calculations, complex I does not show saturation transfer effect in solutions.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"49 12","pages":"777 - 783"},"PeriodicalIF":1.1000,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Possibility of Saturation Transfer in a New Nickel(II) Complex with 2,6-Bis(pyrazol-3-yl)pyridine\",\"authors\":\"D. Yu. Aleshin, I. A. Nikovskii, E. A. Khakina, A. A. Dan’shina, Yu. V. Nelyubina\",\"doi\":\"10.1134/S1070328423700677\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The reaction of N,N '-disubstituted 2,6-bis(pyrazol-3-yl )pyridine ligand (L) with a divalent nickel salt gave a new nickel(II) complex [Ni(L)(H2O)(THF)Cl]BPh4 (I), which was isolated in a pure state and characterized by elemental analysis, mass spectrometry, NMR spectroscopy, and X-ray diffraction (CCDC no. 2221412). According to NMR spectroscopy data combined with the results of quantum chemical calculations, complex I does not show saturation transfer effect in solutions.\",\"PeriodicalId\":759,\"journal\":{\"name\":\"Russian Journal of Coordination Chemistry\",\"volume\":\"49 12\",\"pages\":\"777 - 783\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2023-12-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Coordination Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070328423700677\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328423700677","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

摘要 N,N'-二取代的 2,6-双(吡唑-3-基)吡啶配体(L)与二价镍盐反应得到了一种新的镍(II)配合物[Ni(L)(H2O)(THF)Cl]BPh4 (I)。根据核磁共振光谱数据和量子化学计算结果，络合物 I 在溶液中不显示饱和转移效应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

The Possibility of Saturation Transfer in a New Nickel(II) Complex with 2,6-Bis(pyrazol-3-yl)pyridine

查看原文本刊更多论文

The Possibility of Saturation Transfer in a New Nickel(II) Complex with 2,6-Bis(pyrazol-3-yl)pyridine

The reaction of N,N '-disubstituted 2,6-bis(pyrazol-3-yl )pyridine ligand (L) with a divalent nickel salt gave a new nickel(II) complex [Ni(L)(H₂O)(THF)Cl]BPh₄ (I), which was isolated in a pure state and characterized by elemental analysis, mass spectrometry, NMR spectroscopy, and X-ray diffraction (CCDC no. 2221412). According to NMR spectroscopy data combined with the results of quantum chemical calculations, complex I does not show saturation transfer effect in solutions.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.