A. N. Lukoyanov, N. F. Romashev, V. I. Komlyagina, V. V. Kokovkin, A. V. Cherkasov, A. L. Gushchin
{"title":"氯化钯（II）与单亚氨基苊酮的反应","authors":"A. N. Lukoyanov, N. F. Romashev, V. I. Komlyagina, V. V. Kokovkin, A. V. Cherkasov, A. L. Gushchin","doi":"10.1134/S1070328423601176","DOIUrl":null,"url":null,"abstract":"<p>The reaction of PdCl<sub>2</sub> with [2,6-diisopropylphenyl]iminoacenaphthenone (Dpp-mian) in dichloromethane affords compound [Pd(Dpp-mian)Cl<sub>2</sub>]<sub>2</sub>[Pd(Dpp-mian)<sub>2</sub>Cl<sub>2</sub>] (<b>I</b>). Complex <b>I</b> contains two structural units: [Pd(Dpp-mian)Cl<sub>2</sub>] in which Dpp-mian coordinates to Pd(II) via the bidentate-chelate mode by the nitrogen and oxygen atoms and [Pd(Dpp-mian)<sub>2</sub>Cl<sub>2</sub>] where two Dpp-mian molecules are linked with palladium only via the nitrogen atom. The reaction of PdCl<sub>2</sub> with [4-methoxyphenyl]iminoacenaphthenone (4-MeOPh-mian) in dichloromethane is accompanied by the rearrangement of the ligand structure followed by the formation of the earlier described Pd(II) complex with 1,2-bis[4-methoxyphenyl]iminoacenaphthene (4-MeOPh-bian): [Pd(4-MeOPh-bian)Cl<sub>2</sub>] (<b>II</b>) (CIF file CCDC no. 2280529). Compound <b>I</b> is synthesized for the first time and characterized by X-ray diffraction (XRD) (CIF file CCDC no. 2280528 (<b>I</b>)), phase XRD, elemental analysis, IR spectroscopy, and cyclic voltammetry.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1000,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Reactions of Palladium(II) Chloride with Monoiminoacenaphthenones\",\"authors\":\"A. N. Lukoyanov, N. F. Romashev, V. I. Komlyagina, V. V. Kokovkin, A. V. Cherkasov, A. L. Gushchin\",\"doi\":\"10.1134/S1070328423601176\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The reaction of PdCl<sub>2</sub> with [2,6-diisopropylphenyl]iminoacenaphthenone (Dpp-mian) in dichloromethane affords compound [Pd(Dpp-mian)Cl<sub>2</sub>]<sub>2</sub>[Pd(Dpp-mian)<sub>2</sub>Cl<sub>2</sub>] (<b>I</b>). Complex <b>I</b> contains two structural units: [Pd(Dpp-mian)Cl<sub>2</sub>] in which Dpp-mian coordinates to Pd(II) via the bidentate-chelate mode by the nitrogen and oxygen atoms and [Pd(Dpp-mian)<sub>2</sub>Cl<sub>2</sub>] where two Dpp-mian molecules are linked with palladium only via the nitrogen atom. The reaction of PdCl<sub>2</sub> with [4-methoxyphenyl]iminoacenaphthenone (4-MeOPh-mian) in dichloromethane is accompanied by the rearrangement of the ligand structure followed by the formation of the earlier described Pd(II) complex with 1,2-bis[4-methoxyphenyl]iminoacenaphthene (4-MeOPh-bian): [Pd(4-MeOPh-bian)Cl<sub>2</sub>] (<b>II</b>) (CIF file CCDC no. 2280529). Compound <b>I</b> is synthesized for the first time and characterized by X-ray diffraction (XRD) (CIF file CCDC no. 2280528 (<b>I</b>)), phase XRD, elemental analysis, IR spectroscopy, and cyclic voltammetry.</p>\",\"PeriodicalId\":759,\"journal\":{\"name\":\"Russian Journal of Coordination Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2023-12-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Coordination Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070328423601176\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328423601176","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
摘要
摘要 PdCl2 与[2,6-二异丙基苯基]亚氨基苊酮（Dpp-mian）在二氯甲烷中反应生成化合物 [Pd(Dpp-mian)Cl2]2[Pd(Dpp-mian)2Cl2]（I）。复合物 I 包含两个结构单元：在[Pd(Dpp-mian)Cl2]中，Dpp-mian 通过氮原子和氧原子与 Pd(II)配位，而在[Pd(Dpp-mian)2Cl2]中，两个 Dpp-mian 分子仅通过氮原子与钯相连。PdCl2 与[4-甲氧基苯基]亚氨基苊酮（4-MeOPh-mian）在二氯甲烷中反应时，配体结构发生重排，随后与 1,2-双[4-甲氧基苯基]亚氨基苊酮（4-MeOPh-bian）形成早先描述过的 Pd(II) 复合物：[Pd(4-MeOPh-bian)Cl2] (II)（CIF 文件 CCDC 编号：2280529）。化合物 I 是首次合成，并通过 X 射线衍射 (XRD) （CIF 文件 CCDC 编号：2280528 (I)）、相 XRD、元素分析、红外光谱和循环伏安法进行表征。
Reactions of Palladium(II) Chloride with Monoiminoacenaphthenones
The reaction of PdCl2 with [2,6-diisopropylphenyl]iminoacenaphthenone (Dpp-mian) in dichloromethane affords compound [Pd(Dpp-mian)Cl2]2[Pd(Dpp-mian)2Cl2] (I). Complex I contains two structural units: [Pd(Dpp-mian)Cl2] in which Dpp-mian coordinates to Pd(II) via the bidentate-chelate mode by the nitrogen and oxygen atoms and [Pd(Dpp-mian)2Cl2] where two Dpp-mian molecules are linked with palladium only via the nitrogen atom. The reaction of PdCl2 with [4-methoxyphenyl]iminoacenaphthenone (4-MeOPh-mian) in dichloromethane is accompanied by the rearrangement of the ligand structure followed by the formation of the earlier described Pd(II) complex with 1,2-bis[4-methoxyphenyl]iminoacenaphthene (4-MeOPh-bian): [Pd(4-MeOPh-bian)Cl2] (II) (CIF file CCDC no. 2280529). Compound I is synthesized for the first time and characterized by X-ray diffraction (XRD) (CIF file CCDC no. 2280528 (I)), phase XRD, elemental analysis, IR spectroscopy, and cyclic voltammetry.
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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