三甲基二氯六氯锡酸铵（IV）：晶体结构和 Cl-Cl 非共价相互作用的具体特征

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2023-12-19 DOI:10.1134/S1070328423600213

A. N. Usol’tsev, A. A. Sonina, N. A. Korobeinikov, S. A. Adonin

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引用次数: 0

摘要

摘要氧化碲（IV）与三甲基氯化铵在气态氯存在下于浓盐酸中反应生成超分子二氯六氯ellurate (Me3NH)2{[TeCl6](Cl2)} (I)，其结构由 X 射线衍射 (XRD) 确定（CIF 文件 CCDC 编号 2217752）。元素分析和 X 射线衍射分析数据表明，合成的化合物具有有限的稳定性。拉曼光谱研究了化合物 I 晶体结构中 Cl-Cl 非共价相互作用的具体特征。

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Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions

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Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions

The reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of gaseous chlorine in concentrated hydrochloric acid gives supramolecular dichlorohexachlorotellurate (Me₃NH)₂{[TeCl₆](Cl₂)} (I), whose structure is determined by X-ray diffraction (XRD) (CIF file CCDC no. 2217752). The data of elemental and XRD analyses suggest a restricted stability of the synthesized compound. Specific features of noncovalent Cl···Cl interactions in the crystal structure of compound I are studied by Raman spectroscopy.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.