{"title":"将菱铁矿分解产生的 Fe3O4 用作异相光催化剂，通过活化 PMS 降解 2,4 二氯苯酚","authors":"Hao Wang, Haibo Liu, Ziyang Chu, Fuwei Sun, Xuehua Zou, Qiang Wang, Tianhu Chen, Dong Chen, Hanlin Wang","doi":"10.1016/j.jwpe.2023.104538","DOIUrl":null,"url":null,"abstract":"<div><p>This study showcases the performance of Fe<sub>3</sub>O<sub>4</sub><span><span> (S600) derived from the decomposition of siderite in activating </span>peroxymonosulfate (PMS) for the 2,4-dichlorophenol (2,4-DCP) degradation, as well as the enhancement of visible light in the S600/PMS system. With the involvement of visible light, 2 g/L Fe</span><sub>3</sub>O<sub>4</sub> and 0.5 mM PMS achieved 100 % degradation of 2,4-DCP within 70 min. Singlet oxygen (<sup>1</sup>O<sub>2</sub><span>) and hydroxyl radicals (</span><img>OH) were the primary reactive species responsible for 2,4-DCP degradation under visible light irradiation based on the scavenging experiments and electron paramagnetic resonance (EPR) analysis. Importantly, compared to the absence of visible light, the visible light boosted <sup>1</sup>O<sub>2</sub><span> production and accelerated 2,4-DCP degradation. The effects of various operating parameters on the degradation efficiency were also examined, and the intermediates and possible degradation pathways of 2,4-DCP were identified. This study proves that the integrated utilization of natural siderite derivatives to activate oxidants for pollutant degradation is a promising approach.</span></p></div>","PeriodicalId":17528,"journal":{"name":"Journal of water process engineering","volume":"57 ","pages":"Article 104538"},"PeriodicalIF":6.3000,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fe3O4 derived from the decomposition of siderite as a heterogeneous photocatalyst to degrade 2,4-dichlorophenol via activating PMS\",\"authors\":\"Hao Wang, Haibo Liu, Ziyang Chu, Fuwei Sun, Xuehua Zou, Qiang Wang, Tianhu Chen, Dong Chen, Hanlin Wang\",\"doi\":\"10.1016/j.jwpe.2023.104538\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This study showcases the performance of Fe<sub>3</sub>O<sub>4</sub><span><span> (S600) derived from the decomposition of siderite in activating </span>peroxymonosulfate (PMS) for the 2,4-dichlorophenol (2,4-DCP) degradation, as well as the enhancement of visible light in the S600/PMS system. With the involvement of visible light, 2 g/L Fe</span><sub>3</sub>O<sub>4</sub> and 0.5 mM PMS achieved 100 % degradation of 2,4-DCP within 70 min. Singlet oxygen (<sup>1</sup>O<sub>2</sub><span>) and hydroxyl radicals (</span><img>OH) were the primary reactive species responsible for 2,4-DCP degradation under visible light irradiation based on the scavenging experiments and electron paramagnetic resonance (EPR) analysis. Importantly, compared to the absence of visible light, the visible light boosted <sup>1</sup>O<sub>2</sub><span> production and accelerated 2,4-DCP degradation. The effects of various operating parameters on the degradation efficiency were also examined, and the intermediates and possible degradation pathways of 2,4-DCP were identified. This study proves that the integrated utilization of natural siderite derivatives to activate oxidants for pollutant degradation is a promising approach.</span></p></div>\",\"PeriodicalId\":17528,\"journal\":{\"name\":\"Journal of water process engineering\",\"volume\":\"57 \",\"pages\":\"Article 104538\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2023-12-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of water process engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2214714423010589\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of water process engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2214714423010589","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Fe3O4 derived from the decomposition of siderite as a heterogeneous photocatalyst to degrade 2,4-dichlorophenol via activating PMS
This study showcases the performance of Fe3O4 (S600) derived from the decomposition of siderite in activating peroxymonosulfate (PMS) for the 2,4-dichlorophenol (2,4-DCP) degradation, as well as the enhancement of visible light in the S600/PMS system. With the involvement of visible light, 2 g/L Fe3O4 and 0.5 mM PMS achieved 100 % degradation of 2,4-DCP within 70 min. Singlet oxygen (1O2) and hydroxyl radicals (OH) were the primary reactive species responsible for 2,4-DCP degradation under visible light irradiation based on the scavenging experiments and electron paramagnetic resonance (EPR) analysis. Importantly, compared to the absence of visible light, the visible light boosted 1O2 production and accelerated 2,4-DCP degradation. The effects of various operating parameters on the degradation efficiency were also examined, and the intermediates and possible degradation pathways of 2,4-DCP were identified. This study proves that the integrated utilization of natural siderite derivatives to activate oxidants for pollutant degradation is a promising approach.
期刊介绍：
The Journal of Water Process Engineering aims to publish refereed, high-quality research papers with significant novelty and impact in all areas of the engineering of water and wastewater processing . Papers on advanced and novel treatment processes and technologies are particularly welcome. The Journal considers papers in areas such as nanotechnology and biotechnology applications in water, novel oxidation and separation processes, membrane processes (except those for desalination) , catalytic processes for the removal of water contaminants, sustainable processes, water reuse and recycling, water use and wastewater minimization, integrated/hybrid technology, process modeling of water treatment and novel treatment processes. Submissions on the subject of adsorbents, including standard measurements of adsorption kinetics and equilibrium will only be considered if there is a genuine case for novelty and contribution, for example highly novel, sustainable adsorbents and their use: papers on activated carbon-type materials derived from natural matter, or surfactant-modified clays and related minerals, would not fulfil this criterion. The Journal particularly welcomes contributions involving environmentally, economically and socially sustainable technology for water treatment, including those which are energy-efficient, with minimal or no chemical consumption, and capable of water recycling and reuse that minimizes the direct disposal of wastewater to the aquatic environment. Papers that describe novel ideas for solving issues related to water quality and availability are also welcome, as are those that show the transfer of techniques from other disciplines. The Journal will consider papers dealing with processes for various water matrices including drinking water (except desalination), domestic, urban and industrial wastewaters, in addition to their residues. It is expected that the journal will be of particular relevance to chemical and process engineers working in the field. The Journal welcomes Full Text papers, Short Communications, State-of-the-Art Reviews and Letters to Editors and Case Studies
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