一种蒽衍生物的合成与光电特性

IF 4.7 Q2 NANOSCIENCE & NANOTECHNOLOGY
Darya Khan, Zhang Xiaotao, Muhammad Hasnain Jameel, Mohd Arif Bin Agam, Muhammad Sufi Bin Roslan, Majed A. Bajaber
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引用次数: 0

摘要

基于蒽核分子侧烷基链的π电子骨架,设计了不对称的a侧烷基链蒽衍生物6-(4(-2乙基辛基)苯基)2苯基蒽(EOPPA)。EOPPA是一种坚固、高性能的p型半导体。成功制备了具有最佳溶解度的EOPPA新材料,具有足够的溶解度和热稳定性。EOPPA的不对称结构特性允许通过溶液加工方法在Si/SiO2衬底上制备厚度为100 nm的微米级二维晶体薄膜。高效的溶液法合成EOPPA及其优异的性能表明其在有机电子学领域具有巨大的潜力。EOPPA具有光电性能、晶体结构和良好的薄膜晶体管,其迁移率高于0.18 cm2 V−1 S−1,并且具有高电流开/关比,可以承受近225°C的温度。此外,EOPPA在下一代p型蒽芯有机半导体中表现出良好的潜力,特别是在实际印刷电子应用中。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and optoelectronic properties of an anthracene derivative

An asymmetric a-side alkyl chain anthracene derivative 6-(4 (-2 Ethyl Octyl) Phenyl) 2Phenyl Anthracene (EOPPA) was designed based on a π-electron skeleton with a side alkyl chain of anthracene core molecule. EOPPA was found to be a sturdy and high-performance p-type semiconductor for optoelectronic applications. The creation has successfully made this new material EOPPA with the best solubility, which exhibits both sufficient solvent solubility and thermal stability. The asymmetrical structural features of EOPPA allowed for the preparation of two-dimensional crystalline thin films in micrometer sizes with 100 nm thicknesses on a Si/SiO2 substrate through a solution processing method. The efficient solution processing synthesis of EOPPA and its high performance suggest that it has great potential in the field of organic electronics. The EOPPA demonstrated optoelectronic properties, crystalline structure, and good thin-film transistors having mobilities higher than 0.18 cm2 V−1 S−1, and a high current on/off ratio that can withstand temperatures of almost 225 °C. Furthermore, EOPPA presents good potential to be amongst the next generation of p-type anthracene core organic semiconductors, especially for practical printed electronics applications.

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来源期刊
Micro and Nano Systems Letters
Micro and Nano Systems Letters Engineering-Biomedical Engineering
CiteScore
10.60
自引率
5.60%
发文量
16
审稿时长
13 weeks
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