Sara Bahemmi, Ammar Zobeidi, Salem Atia, Salah Neghmouche Nacer,, Djamel Ghernaout , Noureddine Elboughdiri
{"title":"用 CTAB 活化伊利石高岭石粘土以吸附亚甲基蓝:等温线、动力学和热力学研究","authors":"Sara Bahemmi, Ammar Zobeidi, Salem Atia, Salah Neghmouche Nacer,, Djamel Ghernaout , Noureddine Elboughdiri","doi":"10.52783/tjjpt.v44.i5.2678","DOIUrl":null,"url":null,"abstract":"In this study, a stable multilayered adduct of maghemite surfactant and clay was created by sandwich-like electrostatic self-assembly of cationic polyelectrolytes of cetyltrimethylammonium bromide (CTAB) with illite kaolinite (IKaol) clay. The adsorptive property of IKaol/CTAB towards MB from . Aquatic system uptake was investigated. Its characteristics were analysed using X-ray powder diffraction, Fourier transform-infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, and the zero point of charge. To attain higher performance of the IKaol/CTAB for MB adsorption, the primary key factors that influence the MB dye, such as (A: loading CTAB into the composite matrix of IKaol), adsorbent dose (B: 0.02–0.06 g), pH (C: 4–10), temperature (D: 30–60 °C), and time (E: 5–60 min) , were optimised using the Box–Behnken design method. The obtained results show that the highest MB removal efficiency of 86.24 % was observed at the following significant interactions: AB, BC, and AC and at optimum adsorption operation parameters (A: 0%, B: 0.06 g, C: 7, D: 45◦C, and E: 17.5 min). At these optimum conditions, the best adsorption capacity of MB dye (114.94 mg/g) was recorded at 45°C. The most effective isotherms and kinetic models were the Freundlich and pseudo-second-order kinetic models. The MB dye adsorption mechanism by IKaol can be assigned to several interactions, such as electrostatic attractions, n-π interaction, and hydrogen bonding interactions. The results of this study demonstrate the viability of IKaol as a promising precursor for the creation of an efficient adsorbent that can be used to remove cationic dye from an aqueous environment.","PeriodicalId":39883,"journal":{"name":"推进技术","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Activating Illite kaolinite clay with CTAB for adsorbing Methylene blue: Isotherms, Kinetics, and thermodynamics studies\",\"authors\":\"Sara Bahemmi, Ammar Zobeidi, Salem Atia, Salah Neghmouche Nacer,, Djamel Ghernaout , Noureddine Elboughdiri\",\"doi\":\"10.52783/tjjpt.v44.i5.2678\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this study, a stable multilayered adduct of maghemite surfactant and clay was created by sandwich-like electrostatic self-assembly of cationic polyelectrolytes of cetyltrimethylammonium bromide (CTAB) with illite kaolinite (IKaol) clay. The adsorptive property of IKaol/CTAB towards MB from . Aquatic system uptake was investigated. Its characteristics were analysed using X-ray powder diffraction, Fourier transform-infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, and the zero point of charge. To attain higher performance of the IKaol/CTAB for MB adsorption, the primary key factors that influence the MB dye, such as (A: loading CTAB into the composite matrix of IKaol), adsorbent dose (B: 0.02–0.06 g), pH (C: 4–10), temperature (D: 30–60 °C), and time (E: 5–60 min) , were optimised using the Box–Behnken design method. The obtained results show that the highest MB removal efficiency of 86.24 % was observed at the following significant interactions: AB, BC, and AC and at optimum adsorption operation parameters (A: 0%, B: 0.06 g, C: 7, D: 45◦C, and E: 17.5 min). At these optimum conditions, the best adsorption capacity of MB dye (114.94 mg/g) was recorded at 45°C. The most effective isotherms and kinetic models were the Freundlich and pseudo-second-order kinetic models. The MB dye adsorption mechanism by IKaol can be assigned to several interactions, such as electrostatic attractions, n-π interaction, and hydrogen bonding interactions. The results of this study demonstrate the viability of IKaol as a promising precursor for the creation of an efficient adsorbent that can be used to remove cationic dye from an aqueous environment.\",\"PeriodicalId\":39883,\"journal\":{\"name\":\"推进技术\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"推进技术\",\"FirstCategoryId\":\"1087\",\"ListUrlMain\":\"https://doi.org/10.52783/tjjpt.v44.i5.2678\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"推进技术","FirstCategoryId":"1087","ListUrlMain":"https://doi.org/10.52783/tjjpt.v44.i5.2678","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
Activating Illite kaolinite clay with CTAB for adsorbing Methylene blue: Isotherms, Kinetics, and thermodynamics studies
In this study, a stable multilayered adduct of maghemite surfactant and clay was created by sandwich-like electrostatic self-assembly of cationic polyelectrolytes of cetyltrimethylammonium bromide (CTAB) with illite kaolinite (IKaol) clay. The adsorptive property of IKaol/CTAB towards MB from . Aquatic system uptake was investigated. Its characteristics were analysed using X-ray powder diffraction, Fourier transform-infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, and the zero point of charge. To attain higher performance of the IKaol/CTAB for MB adsorption, the primary key factors that influence the MB dye, such as (A: loading CTAB into the composite matrix of IKaol), adsorbent dose (B: 0.02–0.06 g), pH (C: 4–10), temperature (D: 30–60 °C), and time (E: 5–60 min) , were optimised using the Box–Behnken design method. The obtained results show that the highest MB removal efficiency of 86.24 % was observed at the following significant interactions: AB, BC, and AC and at optimum adsorption operation parameters (A: 0%, B: 0.06 g, C: 7, D: 45◦C, and E: 17.5 min). At these optimum conditions, the best adsorption capacity of MB dye (114.94 mg/g) was recorded at 45°C. The most effective isotherms and kinetic models were the Freundlich and pseudo-second-order kinetic models. The MB dye adsorption mechanism by IKaol can be assigned to several interactions, such as electrostatic attractions, n-π interaction, and hydrogen bonding interactions. The results of this study demonstrate the viability of IKaol as a promising precursor for the creation of an efficient adsorbent that can be used to remove cationic dye from an aqueous environment.