利用 31P NMR 光谱分析废水处理中溶解有机磷的组成特征和转化机理

IF 6.1 2区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL
Yuting Zhang, Wei Shang, SoonThiam Khu, Xingcan Zheng, Yongli Sun, Pengfeng Li, Miao Gu, Wen-an Zhang, Huanmei Ma
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引用次数: 0

摘要

磷成分在污水处理厂(WWTPs)中的迁移和转化对磷的汇聚和循环起着至关重要的作用。然而,由于溶解性有机磷(DOP)性质复杂,其在污水处理厂中的组成和变化尚不清楚,阻碍了对其进行有效检测。本研究全面分析了污水处理厂处理过程中的 DOP 种类及其转化。首先,评估了冻干法和铝盐沉淀法这两种富集方法在促进废水分析方面的有效性。铝盐沉淀法的效果更好,因为它可以通过 31P 核磁共振(31P NMR)光谱鉴定出二级出水中更多的物种:正磷酸盐(Ortho-P)(81.1%-89.3%)、焦磷酸盐(Pyro-P)(0%-2.3%)、正磷酸盐单酯(Mono-P)(7.0%-10.77%)、正磷酸盐二酯(Di-P)(1.0%-2.96%)和膦酸盐(Phos-P)(1.7%-5.16%)。此外,还阐明了磷,尤其是 DOP 在整个污水处理过程中的变化和转化机制。在各处理步骤中,生物处理与三级处理相结合的方法对 DOP 的去除率较高。其中,生物处理主要去除单磷和双磷,去除率分别为 33.3% 和 41.7%。与单磷酸相比,双磷酸的生物利用率更高,更容易被微生物转化和利用。然而,Phos-P 的生物利用率较低,很难被微生物利用,在生物处理中的去除效率仅为 18.4%。在三级处理中,混凝工艺对正磷-酚的去除能力较高(69.1%),对 DOP 的去除率也有部分提高,从而提高了 TP 中 DOP 的比例。此外,Phos-P 无法通过生物处理有效去除,只能通过大颗粒、动物胶或多核羟基络合物的吸附过程部分去除。本研究的结果可为污水处理厂的高效除磷提供理论依据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Composition characterization and transformation mechanism of dissolved organic phosphorus in wastewater treatment using 31P NMR spectroscopy

Composition characterization and transformation mechanism of dissolved organic phosphorus in wastewater treatment using 31P NMR spectroscopy

The migration and transformation of phosphorus components in wastewater treatment plants (WWTPs) play a crucial role in the convergence and circulation of phosphorus. However, the composition and variation of dissolved organic phosphorus (DOP) in WWTPs were unclear because of its complex nature, hindering its efficient detection. In this study, the DOP species and their transformation during the treatment process in WWTP were comprehensively analyzed. First, two enrichment methods were assessed for their effectiveness at facilitating wastewater analysis: lyophilization and aluminum salt precipitation. Aluminum salt precipitation was found to be better because its application allowed 31P nuclear magnetic resonance (31P NMR) spectroscopy to identify more species in the secondary effluent: orthophosphate (Ortho-P) (81.1%–89.3% of the dissolved total phosphorus), pyrophosphates (Pyro-P) (0%–2.3%), orthophosphate monoesters (Mono-P) (7.0%–10.77%), orthophosphate diesters (Di-P) (1.0%–2.96%), and phosphonate (Phos-P) (1.7%–5.16%). Furthermore, the variation and transformation mechanism of phosphorus, particularly those of DOP, during the entire sewage-treatment process were elucidated. Among the treatment steps, biological treatment combined tertiary treatment achieved better DOP removal efficiencies. Therein, biological treatment mainly removed Mono-P and Di-P with removal efficiencies of 33.3% and 41.7% compared with the effluent of the grit chamber. Di-P has higher bioavailability and is more easily converted and utilized by microorganisms than Mono-P. However, Phos-P, with low bioavailability, was hardly utilized by microorganisms, which showed only 18.4% removal efficiency in biological treatment. In tertiary treatment, coagulation process exhibited higher removal ability of Ortho-P (69.1%) and partial removal efficiencies of DOP, resulting in an increase in the DOP proportion in TP. In addition, Phos-P could not be effectively removed through the biological treatment and was only partially reduced via the adsorption process by large particles, zoogloea or multinuclear hydroxyl complexes. The results of this study can provide a theoretical basis for efficient phosphorus removal in WWTPs.

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来源期刊
Frontiers of Environmental Science & Engineering
Frontiers of Environmental Science & Engineering ENGINEERING, ENVIRONMENTAL-ENVIRONMENTAL SCIENCES
CiteScore
10.90
自引率
12.50%
发文量
988
审稿时长
6.1 months
期刊介绍: Frontiers of Environmental Science & Engineering (FESE) is an international journal for researchers interested in a wide range of environmental disciplines. The journal''s aim is to advance and disseminate knowledge in all main branches of environmental science & engineering. The journal emphasizes papers in developing fields, as well as papers showing the interaction between environmental disciplines and other disciplines. FESE is a bi-monthly journal. Its peer-reviewed contents consist of a broad blend of reviews, research papers, policy analyses, short communications, and opinions. Nonscheduled “special issue” and "hot topic", including a review article followed by a couple of related research articles, are organized to publish novel contributions and breaking results on all aspects of environmental field.
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