表面分析洞察注:说明了不确定污染对Pt光电发射峰强度的影响

IF 1.6 4区 化学 Q4 CHEMISTRY, PHYSICAL
Neal Fairley, Pascal Bargiela, Jonas Baltrusaitis
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引用次数: 0

摘要

外来碳污染不仅无处不在,而且用于XPS光谱的电荷参考,而且可以改变跨越结合能大光谱窗口的元素峰的表观存在。本Insight note描述了一个不确定的污染层对Pt的影响,并简要介绍了一种方法,该方法推导了离子束清洁Pt样品的成分光谱,然后可以利用线性数学来峰值拟合所述光谱,从而量化每种成分的量,包括分配给Pt金属污染本身的量。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Surface analysis insight note: Illustrating the effect of adventitious contamination on Pt photoemission peak intensities
Adventitious carbon contaminations are not only omnipresent and used for charge referencing of XPS spectra but also can alter the apparent presence of the element peaks that span over the large spectral window of binding energies. This Insight note describes the effect of an adventitious contamination layer on Pt and presents, in brief, the approach whereby the component spectra are derived for ion beam cleaned Pt samples that can then utilize linear mathematics to peak fit said spectra thus quantifying the amount of each component including that assigned to the contamination itself of Pt metal.
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来源期刊
Surface and Interface Analysis
Surface and Interface Analysis 化学-物理化学
CiteScore
3.30
自引率
5.90%
发文量
130
审稿时长
4.4 months
期刊介绍: Surface and Interface Analysis is devoted to the publication of papers dealing with the development and application of techniques for the characterization of surfaces, interfaces and thin films. Papers dealing with standardization and quantification are particularly welcome, and also those which deal with the application of these techniques to industrial problems. Papers dealing with the purely theoretical aspects of the technique will also be considered. Review articles will be published; prior consultation with one of the Editors is advised in these cases. Papers must clearly be of scientific value in the field and will be submitted to two independent referees. Contributions must be in English and must not have been published elsewhere, and authors must agree not to communicate the same material for publication to any other journal. Authors are invited to submit their papers for publication to John Watts (UK only), Jose Sanz (Rest of Europe), John T. Grant (all non-European countries, except Japan) or R. Shimizu (Japan only).
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