紫外线辐照时间对玻璃/环氧复合材料力学性能的影响

IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES
Hiasmim Rohem Gualberto, João Marciano Laredo dos Reis, Mônica Calixto de Andrade, Hector Reynaldo Meneses Costa, Felipe do Carmo Amorim, Julian David Hunt
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引用次数: 0

摘要

玻璃纤维增强聚合物(GFRP)通常用于户外应用,将其暴露在能够降低其性能的环境条件下,特别是紫外线(UV)辐射。在这项研究中,我们在加速老化室中对GFRP进行了长达180天的紫外线辐射。通过拉伸和弯曲评估对复合材料进行力学测试,同时使用傅里叶变换红外光谱、热重分析和光学显微镜对复合材料的化学和物理变化进行评估。拉伸试验显示,仅在紫外线照射一个月后,GFRP强度就明显降低,在紫外线照射90天时,GFRP强度下降了18.7%。相比之下,复合材料在弯曲测试下的行为表明,在紫外线照射30天后,强度有了初步改善,显著提高了54.1%。随着暴露时间的延长,复合材料的抗弯强度逐渐降低,但在紫外线照射180天后,其强度仍比未老化的复合材料高18.9%。其他表征表明材料降解,以光氧化、复合材料变黄和表面微裂纹等现象为标志。这些因素共同导致了复合材料强度的降低。尽管有明显的降解,但老化后的复合材料可能表现出由于后固化而得到的改善。然而,在更长的时间内,它的机械性能可能会下降。因此,较长的降解时间可能会揭示出一种不同于在较短时间内观察到的行为模式,这取决于所考虑的特定机械载荷。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Effect of Exposure Time to UV Radiation on Mechanical Properties of Glass/Epoxy Composites

Effect of Exposure Time to UV Radiation on Mechanical Properties of Glass/Epoxy Composites

Glass Fiber Reinforced Polymer (GFRP) is commonly used in outdoor applications that expose it to environmental conditions capable of degrading its properties, notably ultraviolet (UV) radiation. In this study, we subjected GFRP to UV radiation for a duration of up to 180 days in an accelerated aging chamber. The composites underwent mechanical testing through tensile and flexural evaluations, while chemical and physical changes in the composite were assessed using Fourier-Transform Infrared Spectroscopy, Thermogravimetric analysis, and optical microscopy. Tensile tests revealed a noticeable reduction in GFRP strength after just one month of UV exposure, with a decrease of 18.7% observed at 90 days of exposure. In contrast, the behavior of the composite under flexural testing showed an initial improvement in strength after 30 days of UV exposure, with a significant increase of 54.1%. With longer exposure times, flexural strength gradually decreased but remained 18.9% higher than the strength of the unaged composite after 180 days of UV exposure. Other characterizations indicated material degradation, marked by phenomena such as photo-oxidation, composite yellowing, and the appearance of microcracks on the surface. These factors collectively contribute to the reduction in composite strength. Despite the visible degradation, the aged composite may exhibit improvements attributed to post-curing. However, over more extended periods, it may experience a decline in mechanical properties. Consequently, longer degradation times may unveil a behavior pattern distinct from what is observed during shorter periods, contingent upon the specific mechanical load under consideration.

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来源期刊
Applied Composite Materials
Applied Composite Materials 工程技术-材料科学:复合
CiteScore
4.20
自引率
4.30%
发文量
81
审稿时长
1.6 months
期刊介绍: Applied Composite Materials is an international journal dedicated to the publication of original full-length papers, review articles and short communications of the highest quality that advance the development and application of engineering composite materials. Its articles identify problems that limit the performance and reliability of the composite material and composite part; and propose solutions that lead to innovation in design and the successful exploitation and commercialization of composite materials across the widest spectrum of engineering uses. The main focus is on the quantitative descriptions of material systems and processing routes. Coverage includes management of time-dependent changes in microscopic and macroscopic structure and its exploitation from the material''s conception through to its eventual obsolescence.
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