Yassine Ennaciri , Mohammed Bettach , Hanan El Alaoui-Belghiti
{"title":"从磷石膏中制备纳米氟化钙和硫酸铵","authors":"Yassine Ennaciri , Mohammed Bettach , Hanan El Alaoui-Belghiti","doi":"10.1080/10426507.2023.2281475","DOIUrl":null,"url":null,"abstract":"<div><p>This study presents an efficient and sustainable procedure for converting phosphogypsum (PG) waste, along with hydrofluoric acid (HF) and ammonia (NH<sub>3</sub>), into valuable materials. The results obtained demonstrate the high efficiency of this proposed procedure, resulting in the synthesis of relatively pure calcium fluoride (CaF<sub>2</sub>) nanoparticles and ammonium sulfate ((NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub>). The latter is recommended for agricultural use as a fertilizer, while the obtained CaF<sub>2</sub> can be utilized in the metallurgical industry. Furthermore, this procedure not only offers a solution for reducing fluorine gas emissions and managing PG waste but also contributes to the conservation of fluorite reserves.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 2","pages":"Pages 178-186"},"PeriodicalIF":1.4000,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Obtaining nano calcium fluoride and ammonium sulfate from phosphogypsum\",\"authors\":\"Yassine Ennaciri , Mohammed Bettach , Hanan El Alaoui-Belghiti\",\"doi\":\"10.1080/10426507.2023.2281475\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This study presents an efficient and sustainable procedure for converting phosphogypsum (PG) waste, along with hydrofluoric acid (HF) and ammonia (NH<sub>3</sub>), into valuable materials. The results obtained demonstrate the high efficiency of this proposed procedure, resulting in the synthesis of relatively pure calcium fluoride (CaF<sub>2</sub>) nanoparticles and ammonium sulfate ((NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub>). The latter is recommended for agricultural use as a fertilizer, while the obtained CaF<sub>2</sub> can be utilized in the metallurgical industry. Furthermore, this procedure not only offers a solution for reducing fluorine gas emissions and managing PG waste but also contributes to the conservation of fluorite reserves.</p></div>\",\"PeriodicalId\":20056,\"journal\":{\"name\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"volume\":\"199 2\",\"pages\":\"Pages 178-186\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1042650723002411\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650723002411","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Obtaining nano calcium fluoride and ammonium sulfate from phosphogypsum
This study presents an efficient and sustainable procedure for converting phosphogypsum (PG) waste, along with hydrofluoric acid (HF) and ammonia (NH3), into valuable materials. The results obtained demonstrate the high efficiency of this proposed procedure, resulting in the synthesis of relatively pure calcium fluoride (CaF2) nanoparticles and ammonium sulfate ((NH4)2SO4). The latter is recommended for agricultural use as a fertilizer, while the obtained CaF2 can be utilized in the metallurgical industry. Furthermore, this procedure not only offers a solution for reducing fluorine gas emissions and managing PG waste but also contributes to the conservation of fluorite reserves.
期刊介绍:
Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.