Xue Shi, Jia-Wei Qiao, Sang Yong Jeong, Peng Lu, Xiao-Yan Du, Hang Yin, Wei Qin, Han Young Woo, Xiao-Tao Hao
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Synergistic effects of hole blocking and Förster resonance energy transfer process in high-performance photomultiplication organic photodetectors
Organic photodetectors (OPDs) are a potential next-generation photodetection technology because they are lightweight, flexible, and have customizable spectral responses. However, high dark currents with low detectability remain major challenges, limiting the widespread application of photomultiplication OPDs (PM-OPDs). This work describes a straightforward interface modification strategy based on the PBDB-T:N2200 bulk heterojunction (BHJ) structure to improve the PM-OPD performance. Introducing a thin rubrene layer achieves the synergistic effects of hole blocking and the Förster resonance energy transfer (FRET) process, resulting in a two-order-of-magnitude reduction in dark current density and an increased responsivity of 19.77 A W−1 at 660 nm. Moreover, the external quantum efficiency improves significantly through FRET, and a specific detectivity of 4.39 × 1013 Jones is demonstrated at 660 nm, which is the highest value among existing PM-OPDs, using BHJ structures. An impressive increase in the linear dynamic range from 91 to 144 dB was obtained due to the improved photocurrent density and balanced charge transport. The broad applicability of the strategy was verified through a PM6:Y6-based OPD system. Our approach offers more general application prospects by improving the detection capability of photodetectors for low-light environments.
期刊介绍:
Applied Physics Letters (APL) features concise, up-to-date reports on significant new findings in applied physics. Emphasizing rapid dissemination of key data and new physical insights, APL offers prompt publication of new experimental and theoretical papers reporting applications of physics phenomena to all branches of science, engineering, and modern technology.
In addition to regular articles, the journal also publishes invited Fast Track, Perspectives, and in-depth Editorials which report on cutting-edge areas in applied physics.
APL Perspectives are forward-looking invited letters which highlight recent developments or discoveries. Emphasis is placed on very recent developments, potentially disruptive technologies, open questions and possible solutions. They also include a mini-roadmap detailing where the community should direct efforts in order for the phenomena to be viable for application and the challenges associated with meeting that performance threshold. Perspectives are characterized by personal viewpoints and opinions of recognized experts in the field.
Fast Track articles are invited original research articles that report results that are particularly novel and important or provide a significant advancement in an emerging field. Because of the urgency and scientific importance of the work, the peer review process is accelerated. If, during the review process, it becomes apparent that the paper does not meet the Fast Track criterion, it is returned to a normal track.