双分子光氧化系统中的有机光氧化反应。

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chemical record Pub Date : 2023-12-05 DOI:10.1002/tcr.202300326

Prof. Yasuharu Yoshimi

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引用次数: 0

摘要

本报告利用我们最近的相关成果，展示了双分子光复氧系统与单分子光复氧系统相比的反应特性。在双分子光复氧体系中，光诱导和背电子传递等电子传递过程的效率较低，因此会通过不同的途径产生独特的产物。在这一体系中，用适当的氧化/还原电位轻松替换光氧化催化剂为光氧化反应提供了宝贵的见解。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Organic Photoredox Reactions in Two-Molecule Photoredox System

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Organic Photoredox Reactions in Two-Molecule Photoredox System

Using our recent relevant results, this account shows the featured reactivities of two-molecule photoredox systems compared to one-molecule photoredox systems. The low efficiency of electron transfer processes, such as photoinduced and back-electron transfer, in the two-molecule photoredox system, furnishes unique products through different pathways. The facile replacement of photoredox catalysts with appropriate oxidation/reduction potentials in this system provides valuable insights into photoredox reactions.

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来源期刊

Chemical record 化学-化学综合

CiteScore

11.00

自引率

3.00%

发文量

188

审稿时长

>12 weeks

期刊介绍： The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.